Unit 1: Section 5: Kinetics Flashcards

1
Q

What is collision theory

A

Two particles won’t react with each other unless they are facing in the right direction and they are colliding with at least a certain minimum amount of kinetic energy

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
2
Q

What is activation energy

A

The minimum amount of kinetic energy particles need to react

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
3
Q

What are the Maxell-Boltzmann distributions

A

Some molecules in a substance will have lots of kinetic energy, some will have a low amount of kinetic energy but most will have a moderate amount of kinetic energy

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
4
Q

Describe what the Maxell-Boltzmann distribution model looks like on a graph

A

Sharp increase in y in the beginning
The peak of the curve represents the most likely kinetic energy of any single molecule
The mean energy of all the molecules is slightly to the right to the peak
Most molecules operate between these two points
Then the graph gradually dips and levels out a small number of molecules

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
5
Q

What does the area under the Maxell-Boltzman distribution curve represent

A

The amount of molecules in a substance

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
6
Q

What does increasing the temperature of a reaction do to the Maxell-Boltzmann distribution curve

A

It shifts it to the right

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
7
Q

What does increasing the concentration of molecules in a reaction do to the Maxell-Boltzmann distribution curve

A

It increases the peak of the curve

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
8
Q

What does a catalyst do

A

Provides an alternative reaction pathway that has a lower activation energy

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
9
Q

What catalyst is used in tha Haber-Bosch process

A

An iron catalyst

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
10
Q

How does a catalyst affect the Maxell-Boltzmann distribution curve

A

It does’nt effect it because the same out of energy is present but theres just an alternative reaction pathway

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
11
Q

What is the reaction rate

A

The change in the amount of a reactant or product over time

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
12
Q

What is the formula for the rate of reaction

A

Rate of reaction = Amount of reactant used or product formed/time

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
13
Q

What are the three ways to follow a reaction to find out the rate of reaction

A

The change in mass
Time taken for precipitate to form
Gas volume

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
14
Q

Explain how to measure the rate of reaction using the time taken for a precipitate to form

A

You can use this method when product’s a precipitate that clouds a solution
Stand conical flask on top of white tile with a black cross on it
Add fixed volumes of reactant solutions to the flask and start a stopwatch and the stop the timer when the mark isn’t visible

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
15
Q

Explain how to measure the rate of reaction using the the change in mass

A

When the product is a gas, its rate of formation can be measured using a mass balance
Put conical flask with reactants on a balance to measure the mass
When the reaction starts record the mass at regular intervals into a table with time and mass as the two variables
The reaction stops when the mass balance stops decreasing

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
16
Q

What precautions should you take when measuring the rate of reaction using the change in mass method

A

Conduct reaction in a fume cupboard because reaction can release dangerous gases

17
Q

Explain how to measure the rate of reaction using the the volume of gas

A

If gas is given off during a reaction, you can collect it in a gas syringe and record how much you’ve got a regular time intervals
Get a conical flask, put the reactants in and place a bung and a gas syringe through the bung
Start a timer when the reaction starts and read off volume in the gas syringe at regular intervals
You know the reaction is finished when the volume stops decreasing

18
Q

Explain why using the volume of a gas given off in a reaction to calculate the rate of reaction is an accurate method

A

Gas syringes give volumes to the nearest 0.1cm^3
No gas escapes so you get a very accurate reading