Unit #1 Review Session Cards sheet 2 Flashcards
What are hydrophobic interactions, and why are they important for living organisms?
They are nonpolar and not charged; they interact with other hydrophobic molecules
- Water repels them / pushes hydrophobics away
- Water excludes these molecules forcing them to associate with each other
*H2O determines shape of biopolymers
Why do water and oil separate after you shake them up?
Water will force/push oil away
*Oil is nonpolar
Ex: water pushes hydrophobic molecules away and forms shape of protein
*Protein shape not right = disorder b/c can’t function right
What is a mole (to a chemist)?
Quantity of a chemical that contains avogadro’s number
*Easier to weigh molecules than count them
What is pH and why is it important to living organisms?
- name of 2 ions
- scale
- neutral
- which way means what
H2O → H+ + OH-
Water (pH = 7) → proton/hydrogen ion + hydroxyl
0————7————14
pH scale runs from 0 to 14
7 is neutral
From 7 to 0…the number of OH- decreases and the number of H+ increases
Solution becomes more acidic
From 7 to 14…the number of OH- increases and the number of H+ decreases
Solution becomes more basic
In living systems, pH must remain constant
pH of blood = 7.4
What is the difference in [H+] between a solution whose pH is 5 and a solution whose pH is 8?
5-6-7-8
X 10 each time to the right
1000 or 10^3 more protons in 5 than 8
What is a buffer?
Minimizes change in H+ or OH- concentrations in a solution
What is the formula for determining pH?
pH = -log [H+]
Which pH ion is acidic and which is base?
proton / hydrogen ion = acidic
hydroxyl = basic
Why is life based on carbon?
Needs 4 electrons Shares them (covalent bond)
C IS A great covalent bonder
*forms backbone of many biopolymers
What is a functional group (in organic chemistry) and why are they so important?
Groups of atoms that confer certain chemical properties on the molecules in which they are found
Please list the 7 most important functional groups in biological molecules.
- OH hydroxyl
- CO carbonyl
- COOH carboxyl
- CH3 methyl (nonpolar)
- SH sulfhydryl
- PO4 phosphate (add energy)
- NH2 amino (basic)
What is a macromolecule, and what features do all macromolecules have in common?
Large molecule
Polymer of similar polar units
What types of macromolecules do you find in living organisms?
Polymers ( - monomers)
Polysaccharides (carbohydrates)
- Monosaccharides
- Disaccharides
Proteins
*Amino acids
Lipids
*Fat is made of fatty acids and glycerol
Nucleic acids
*nucleotides
What is a dehydration reaction?
Used to build a polymer from its monomers
H+ and OH- → H2O
What is an anabolic reaction?
What is a catabolism reaction?
Reaction that builds
*ex: dehydration
Catabolism: reaction breaks down hydrolysis
What is a hydrolytic reaction?
Used to break down a polymer into its monomers
Add water into bond to separate
Ex: Bread into water
Digestion of food
What is a carbohydrate, and what functions do carbohydrates perform?
Sugar functions:
Source of energy
Structure
Signaling - these molecules are used for cell to cell communication
Why are carbohydrates good for storing energy?
C-H
Carbohydrates have a large number of C-H bonds
What is an isomer?
Isomer: molecules with the same structural formula, but atoms are arranged differently
C6H12O6 is the structural formula for three sugars:
Glucose
Fructose
Galactose
** atoms are arranged differently
Difference between isomers and isotopes?
isomers =
molecules
same structural formula
different arrangement
isotopes =
element
different # of neutrons
different atomic masses
suffix: “ose”
sugar
suffix: “ase”
enzyme
What is the difference between a structural isomer and a stereoisomer?
Structural isomers: have functional groups attached to different C (which C the O is on)
Stereoisomer: have functional groups attached in different orientations, but functional groups on the same C (which side the hydroxyl is attached to the carbon)
What is a transport disaccharide?
Made from 2 monosaccharides
These disaccharides are made by plants to keep the sugars from being metabolized as they pass down to the roots for storage
*plant cells would grab and use monosaccharides for energy
Maximizes the amount of sugar that gets stored in the root
What is the similarity between starch, glycogen and cellulose?
Starch, glycogen, and cellulose are all polymers of glucose
What is Alpha and Beta glucose?
Alpha glucose: hydroxyl on bottom
Beta glucose: hydroxyl on top
What linkages do the following have?
starch
glycogen
cellulose
Starch: 1-4 linkage
Glycogen: 1-6 linkages
Cellulose: 1-4 linkages
What kind of glucose are the following:
starch
glycogen
cellulose
Starch: polysaccharide polymer of alpha-glucose
Glycogen: polysaccharide polymer of alpha-glucose
Cellulose: polysaccharide polymer of beta-glucose