Unit 1 Flashcards

1
Q

What is Organic Chemistry?

A

Science related to carbon-containing molecules (Can also include H, O, N, and Halogens (F, Cl, Br, I))

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2
Q

What is the Octet rule?

A

The rule is that all atoms want to have a full valance shell

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3
Q

What is the formula to figure out formal charges?

A

Total # of valance electrons - (# of non bonding electrons + # of bonds)

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4
Q

What are the ways (for atoms) to get a positive charge?

A
  1. Lose electrons
  2. When an atom has an extra bond when compared to its neutral state it will be positively charged
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5
Q

What are the ways (for atoms) to get a negative charge?

A
  1. Gain electrons
  2. When an atom has one less bond when compared to its neutral state it will be negative
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6
Q

What are the exceptions to the octet rule?

A

Boron (B) and Aluminum (Al)

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7
Q

What is electronegativity?

A

The tendency of an atom to grab an electron

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8
Q

What is the relationship between Atomic #, Size, and Electronegativity?

A

As atomic # rises so does electronegativity, and as size increases electronegativity decreases. The top right is the most electronegative.

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9
Q

What is a covalent bond?

A

It’s a bond between two nonmetals in which they share the electrons.

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10
Q

What’s the difference between polar and nonpolar covalent bonds?

A

Non-polar bonds do not have poles, whereas polar covalent bonds do have poles due to differences in electronegativity

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11
Q

What is a dipole moment?

A

It shows polarity using the formula (sum of charges x distance)

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12
Q

What are popular Nonpolar covalent bonds?

A

H-H, C-H, C-C

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13
Q

What are the electronegativity differences between the different type of bonds?

A

<.5 Nonpolar covalent bonds
.5<X<1.9 Polar Covalent bonds
>1.9 Ionic bonds

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14
Q

What could you compare the behavior of atomic-orbitals to?

A

Waves

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15
Q

What do two s orbitals combine to form?

A

They form 2 sigma orbitals (Sigma bonding orbital (Lower energy) and Sigma anti bonding orbital (Higher energy))

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16
Q

What does the parallel overlapping of two p orbitals create?

A

Pi orbitals (Double bonds) which also have a bonding (lower energy) and anti bonding (higher energy) molecular orbital

17
Q

How is an sp orbital made?
How is an sp2 orbital made?
How is an sp3 orbital made?

A

Sp refers to an s orbital that combines with how every many p orbitals come together.

18
Q

How do you know which version of sp hybridization belongs to a specific atom?

A

Double bonds and Triple bonds cause pi bonds. When there are no pi bonds it is sp3 when there is one pi bond it is sp2 and when there is 2 pi bonds it is sp.

19
Q

What is a resonant structure?

A

It’s the same molecule with the electrons distributed differently.

20
Q

What does the curved arrow of a resonance structure show?

A

It shows the movement of electrons from the electron source to the electron sink