U2S2 halide ions Flashcards
What s a halide ion
Group 7 element gains an electron to form a 1- ion
What happens when a halide ion takes place in a redox reaction
Reduces something and is oxidised itself
What is the trend in reducing power of halides as go down group
- increases
- more distance and shielding means weaker attraction
What is the role of the halide ions and sulfuric acid when the two react
- halide ions are reducing agents
- sulfuric acid is oxidising agent
What is the reaction for NaCL/NaF with sulfuric acid
H2SO4(l) + NaCl(s) -> NaHSO4(s) + HCl(g)
- misty fumes
What is the reaction of NaBr with sulfuric acid
2H2SO4(l) + 2NaBr(s) -> Na2SO4(s) + Br2(g) + SO2(g) + 2H2O(l)
- choking fumes of SO2 and orange fumes of Br2
What is the reaction of NaI with sulfuric acid
NaI(s) + H2SO4(l) -> NaHSO4(s) + HI (g)
2HI(g) + H2SO4(l) -> I2 + SO2(g) +2H2O(l)
6HI(g) + SO2 -> H2S(g) + 3I2(s) + 2H2O(l)
- fumes of H2S and solid iodine