U2S2 halide ions Flashcards

1
Q

What s a halide ion

A

Group 7 element gains an electron to form a 1- ion

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2
Q

What happens when a halide ion takes place in a redox reaction

A

Reduces something and is oxidised itself

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3
Q

What is the trend in reducing power of halides as go down group

A
  • increases
  • more distance and shielding means weaker attraction
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4
Q

What is the role of the halide ions and sulfuric acid when the two react

A
  • halide ions are reducing agents
  • sulfuric acid is oxidising agent
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5
Q

What is the reaction for NaCL/NaF with sulfuric acid

A

H2SO4(l) + NaCl(s) -> NaHSO4(s) + HCl(g)
- misty fumes

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6
Q

What is the reaction of NaBr with sulfuric acid

A

2H2SO4(l) + 2NaBr(s) -> Na2SO4(s) + Br2(g) + SO2(g) + 2H2O(l)
- choking fumes of SO2 and orange fumes of Br2

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7
Q

What is the reaction of NaI with sulfuric acid

A

NaI(s) + H2SO4(l) -> NaHSO4(s) + HI (g)
2HI(g) + H2SO4(l) -> I2 + SO2(g) +2H2O(l)
6HI(g) + SO2 -> H2S(g) + 3I2(s) + 2H2O(l)
- fumes of H2S and solid iodine

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