U1 - Trends of the Periodic Table Flashcards
•Atomic Radius
•Distance between the nucleus and valence e-
•Effective Nuclear Charge (Zeff)
•Describes strength of attraction between nucleus and valence e-
•Law of Electrostatics
- Unlike charges attract
* Like charges repel
•Effective Nuclear Charge and Radius Size
- On the same period:
- More protons means greater Zeff
- Smaller radius
- More protons = Greater Zeff
•Shielding Effect
- To decrease Zeff
* Number of filled orbitals between the nucleus and the valence e-
•Shielding Effect, Effective Nuclear Charge, and Radius Size
- The greater the shielding effect, the weaker the Zeff, the larger the radius
- The weaker the shielding effect, the stronger the Zeff, the smaller the radius
- The shielding effect does not matter and more protons, stronger Zeff, smaller radius
- The shielding effect does not matter and less protons, weaker Zeff, bigger radius
•Ionization Energy
•The amount of energy needed to remove a valence e-
•Ionization Energy General Formula
- A = any element
* A + energy –> A (+) + e-
•Ionization Energy, Zeff, Radius Size
- Larger radius = Less ionization energy
- Less Zeff = Less ionization energy
- Smaller radius = More ionization energy
- More Zeff = More ionization energy
- 1st Ionization
- 2nd Ionization
- General Equation
•A = any element
- Amount of energy required to remove the 1st e-
- A + energy –> A (+) + e-
- Amount of energy required to remove the 2nd e-
- A (+) + ENERGY –> A (2+) + e-
•After loss of first e-, there will be less e- for the remaking e-, so increase in Zeff and increase in ionization energy
•Ionization Energy Trends in the Periodic Table
- Left to right in a period = Increase in ionization energy
* Up to down in a group = Decrease in ionization energy
•Electron Affinity
•The energy absorbed or released when an electron is added to a neutral atom
•Electron Affinity Trends in the Periodic Table
- Left to right in a period = Increase in electron affinity
- Up to down in a group = Decrease in electron affinity
- Reversed for noble gases
•Electronegativity
- The relative ability of an atom to attract shared electrons
- Value is found on the periodic table
•Electronegativity Trends in the Periodic Table
- Left to right in a period = Increase in electronegativity
* Up to down in a group = Decrease in electronegativity