Trends in Periodic Table (MEMORISE) Flashcards
What is Core Charge/Nuclear Charge? How do you calculate Core Charge?
The Core Charge is a measure of the attractive force felt by the valence shell electrons towards the nucleus.
Core Charge is calculated by the number of protons in the nucleus MINUS the number of total inner shell electrons (Number of electrons EXCLUDING THE VALENCE SHELL)
Thus,
Number of Protons - Number of Total-Inner Shell Electrons
- As the core charge increases, the valence electrons are more strongly attracted to the nucleus, meaning it is harder to lose them.
What is the trend in core charge across the periodic table?
The core charge STAYS THE SAME
down the group
The core charge INCREASES across the period
What happens to the atomic radius in the periodic table?
The atomic radius increases down the group
The atomic radius DECREASES ACROSS THE PERIOD
What is the atomic radius? How do you calculate or find the atomic radius?
The atomic radius is a measurement used for the size of atoms.
It is the total distance from an atom’s nucleus to the outermost electron shell
The atomic radius is found by halving the distance between the nuclei of two atoms of the same element.
What happens to the atomic radius down the group and across the period?
What is the reason behind these properties/ trends?
The atomic radius increases down the group
The atomic radius decreases across the period. (Left to Right)
The atomic radius increases Down the Group because the number of electron shells increases, meaning that it gets bigger and bigger, further away from the nucleus of the atom.
Also, the atomic radius decreases across the period since the electrostatic attraction increases. Across the period, the number of protons tends to increase. The greater the number of protons and negative electrons, the greater the attractive force and therefore the core charge. (Since core charge is number of protons - number of total inner electrons)
Thus, what is the relationship between core charge and atomic radius?
As the core charge increases, the valence electrons are more strongly attracted to the nucleus, which means that the atomic radius decreases.
This is since the atom ‘contracts’ and pulls the **electron cloud ** closer to the nucleus, when having a higher core charge, resulting in less distance of the valence electron shell to the atoms nucleus.
What is electronegativity? What is its relationship with core charge?
Electronegativity is the tendency to gain electrons.
The more strongly the valence electrons of an atom are attracted to the nucleus of the atom, the greater the electronegativity/ tendency to gain electrons.
(Think of it like a magnet. Once u throw sth like a nail, it instantly attaches itself due to the magnetic force/attraction)
This also means that weaker bonds between the valence electrons and the nucleus, mean less chance for the atom to gain electrons
What are the trends of electronegativity in the periodic table?
The electronegativity DECREASES down the GROUP
and
INCREASES across the PERIOD
What are the trends of metal reactivity and non-metal reactivity?
Metal reactivity:
INCREASES DOWN THE GROUP
DECREASES ACROSS THE PERIOD
Non-Metal Reactivity:
DECREASES DOWN THE GROUP
INCREASES ACROSS THE PERIOD
What is first ionisation energy?
FIRST IONISATION ENERGY is the energy required to remove ONE electron from an atom of an element in its GAS PHASE.
What is ionisation in general?
Ionisation is the process of removing an electron from an atom and forming an ion called ionisation.
List the pattern/trend of Ionisation Energy
List reasons why
Ionisation energy decreases down the group.
This is because the number of electron shells increases down the group, meaning there is less attraction of the valence electrons towards the centre. It is held less tightly and requires less energy to move, making it easier to lose an electron rather than to gain.
Ionisation Energy INCREASES ACROSS THE PERIOD
This is because the atomic radius decreases across the period, meaning it is harder to remove an electron from an outer shell.2
(since smaller distance between valence electrons to nucleus, imply stronger bonds, making it less easier to lose electrons) Thus, MORE ENERGY IS REQUIRED TO LOSE THIS ELECTRON WILLINGLY.
What is the relationship between atomic radius and electron shells?
Increased electron shells mean increased atomic radius, as the distance from the nucleus of the atom gets bigger and bigger.
Does the size of the atom affect the core charge?
Yes. Atomic radius and core charge vary upon one another. A smaller atomic radius would mean a greater core charge while a bigger atomic radius would mean lower core charge..
An exception is the core charge remains the same down the group.
What does higher and smaller atomic radius imply?
A bigger atomic radius implies that the distance between the valence electrons to its nucleus is larger, meaning that there is less pull and thus easier for the atom to lose electrons. (Since bigger means weaker attraction)
A smaller atomic radius implies that valence electrons are tighter and closer to the nucleus, meaning it is harder to lose electrons. Hence, they have a stronger attraction.