transition elements Flashcards

1
Q

what is a transition element

A

d-block elements that form at least one ion with a partailly filled d-orbital

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2
Q

dblock but not trans (2)

A
  • scandium
  • zinc
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3
Q

cr3+ metal aqua ion

A

violet soloution
[Cr(H2O)6] 3+

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4
Q

Fe 2+ metal aqua ion

A

Green solution
[Fe(H2O)6] 2+

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5
Q

Fe 3+ metal aqua ion

A

yellow
[Fe(H2O)6] 3+

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6
Q

mn2+ metal aqua ion

A

pale pink soloution
[Mn(H2O)6] 2+

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7
Q

cu 2+ metal aqua ion

A

Blue solution
[Cu(H2O)6] 2+

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8
Q

cr3+ with oh -

A

Green precipitate
Cr(OH)3(H2O)3

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9
Q

fe2+ with oh-

A

Green precipitate
Fe(OH)2(H2O)4

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10
Q

fe3+ with oh -

A

Brown precipitate
Fe(OH)3(H2O)3

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11
Q

mn2+ with oh -

A

Pale brown precipitate
Mn(OH)2(H2O)4

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12
Q

cu2+ with oh -

A

Blue precipitate
Cu(OH)2(H2O)4

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13
Q

cr3+ and excess oh-

A

Green solution
[Cr(OH)6]3

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14
Q

fe2+ and excess oh-

A

No change

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15
Q

fe3+ and excess oh-

A

No change

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16
Q

mn2+ and excess oh-

17
Q

cu2+ and excess oh-

18
Q

cr3+ with nh3

A

Green precipitate
Cr(OH)3
(H2O)3

19
Q

fe2+ with nh3

A

Green precipitate
Fe(OH)2
(H2O)4

20
Q

fe3+ with nh3

A

Brown precipitate
Fe(OH)3
(H2O)3

21
Q

mn2+ with nh3

A

Pale brown precipitate
Mn(OH)2
(H2O)4

22
Q

cu3+ with nh3

A

Blue precipitate
Cu(OH)2
(H2O)4

23
Q

cr3+ with nh3 excess

A

Purple solution
[Cr(NH3
)6
]
3+

24
Q

fe2+ with nh3 excess

25
fe3+ with nh3 excess
No change
26
mn2+ with nh3 excess
No change
27
cu2+ with nh3 excess
Dark blue solution [Cu(NH3 )4 (H2O)2 ] 2+