group 2 Flashcards

notes --> flashcards

1
Q

alkaline earth metals

A

all group 2 have hydroxides that are alkaline

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2
Q

physical properties- group 2

A

high mp/bp
light metals with low densities
form colourless (white compounds)

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3
Q

stable electronic structure

A

the atoms of the elements have a tendency to lose 2 electrons in their outer shells to form a stable electronic structure

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4
Q

ionisation energy as you go down the group-2

A

the ionisation energy decreases due to the increasing atomic radius and shielding effect , so there is a weaker positive attraction from the nucleus

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5
Q

highest energy electron in … shell

A

s sub - shell (in the s block )

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6
Q

ionisation of the elements - {m= any group2}

A

M –> M+ + e- {oxidation first state }
M + –> M2+ + e- {+2 oxidation state }

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7
Q

reactive metals are oxidised to produce

A

2+ ions

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8
Q

are ….. reducing agents

A

strong

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9
Q

reactivity …. down a group

A

increases - easier to lose electrons

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10
Q

group 2 elements form … ions

A

positive (cation)

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11
Q

group 2 elements

A

Be, Mg, Ca, Sr, Ba, Ra

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12
Q

reactions with oxygen - redox- g2

A
  • react vigorously
  • ionic oxide MO eg. calcium oxide = CaO
    2Ca(g) + O2(g) –> 2CaO(s)
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13
Q

reactions with water - g2

A
  • all group 2 elements except beryllium, react with water to form hydroxides
  • general formula M(OH)2
  • and H (gas)
  • mg reacts with water very slowly
  • going down the group each metal reacts more vigorously with water
  • redox reaction - metal is oxidised and hydrogen is reduced
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14
Q

reactions with dilute acid- g2

A

all group 2 elements except Be react with dilute acids to form a salt and hydrogen gas
- more vigorous down the group

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15
Q

reaction with oxides and water- g2

A

group 2 oxides react with water to form metal hydroxides and the general reaction for this (m )
MO(s) + H2O –> M(OH)2 (aq)
- metal hydroxides are soluble in water and form alkaline solutions with water because they release OH- ions and the typical PH is 10-12

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16
Q

solubility- g2

A

the solubility of hydroxides in water increases down the group, meaning if a hydroxide is more soluble it will release more oh- ions forming an alkaline solution with a higher ph.
beryllium is at the top of the group and is insoluble in water
Magnesium forms Mg(OH) 2 (s) which is only slightly soluble in water – the resulting
solution is dilute with a comparatively low OH - (aq) concentration
Ba(OH) 2 (s) is much more soluble in water than Mg(OH) 2 (s) and so has a higher OH -
concentration therefore, the resulting solution is more alkaline than a solution of Mg(OH) 2

17
Q

thermal decomposition - g2

A
  • Carbonates decompose at higher temperatures down the group
  • Thermal decomposition gets harder as you go down the group
  • MgCO 3 (s)  MgO(s) + CO 2 (g)
18
Q

uses - compounds - g2

A

The oxides, carbonates and hydroxides of group 2 metals are basic – this means they will react with acids to form a salt and water
- As these reactions with hydrochloric acid take place, you will see a solid oxide or hydroxide ‘dissolve’
- The alkalinity of group 2 metal compounds has resulted in them being used for a number of purposes, where neutralising acids is important and they are also important substances in the construction industry

19
Q

neutralising acidic soils

A

Calcium hydroxide is used by farmers and gardeners as
‘lime’ and it is used to reduce the acidity levels of soil

20
Q

g2- indigestion remedies

A

Human stomachs contain a small amount of
hydrochloric acid so when we suffer from indigestion, there is a build-up of too much of this acid
- Many indigestion remedies are available, for example ‘milk of magnesia’ which contains magnesium hydroxide which neutralises the excess acid producing a salt and water
- This is a weak alkali so
doesn’t damage stomach
tissues

21
Q

building and construction uses

A
  • One of the group 2 metal carbonates, calcium carbonate, is an extremely useful building material – it is present in both limestone and marble
  • It is by far the most important calcium compound industrially – it is used in the building trade and in the manufacture of glass and steel
  • However, calcium carbonate reacts readily with acids for example rainwater has an acidic pH which leads to gradual erosion of objects made using limestone or marble