Topic 8 Flashcards
What are standard conditions
100kPa
298 K
what is enthalpy change
the heat energy change measured at constant pressure
exothermic enthalpy diagram
reactants higher than products
activation energy at top of curve
enthalpy change the distance from reactants line to products line
endothermic enthalpy diagram
reactants lower than products
activation energy at top of curve
enthalpy change the difference between reactant line and product line
standard enthalpy of reaction definition (tube sign r)
enthalpy change for a given reaction under standard conditions (and in the molar quantities given in chemical equation)
standard enthalpy of formation definition (tube sign f)
enthalpy change when one mole is formed from elements in their standard States
standard enthalpy of combustion definition (tube sign c)
enthalpy change when one mole of a substance is completely burned in oxygen under standard conditions
standard enthalpy of neutralisation definition
tube sign neut
enthalpy change when one mole of water is produced from the reaction between an acid and a base under standard conditions
measuring enthalpy changes
q= m x c x change in temp
-q / moles = enthalpy change
bond breaking is
endothermic (requires energy)
bond forming is
exothermic (releases energy)
working out enthalpy change of a reaction
bond broken enthalpy - bonds formed enthalpy
working out the rate of a reaction
change in concentration per second
also the gradient of a concentration time graph