Topic 4b Flashcards
trend in melting and boiling point of halogens
increases down the group as the molecules get bigger so there are more and stronger van der waal forces
trend in electro negativity of halogens
decreases down the group due to more shielding of the nucleus charge
trend in reactivity of the halogens
less reactive down the group due to more shielding and distance from the nucleus so the electron is less likely to be attracted
halogen redox reactions
the more reactive halogen replaces the halide ion
if bromide is displaced the mixture will be orange
if iodide is displaced the mixture will be brown
add a organic solvent (hexane)and shake
instead there is orange bromine layer
and purple iodine layer
trend in reducing power of halides
increases down the group as the electron is further from the nucleus and there is more shielding
test for ammonium compounds
add sodium hydroxide to substance and gently heat
hold red litmus paper and it will go blue