Topic 7 Flashcards

1
Q

Carbohydrates

A
  • important source of energy
  • used for cell-cell recognition
  • a coating to protect cells/ entire organisms
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2
Q

Simplest Carbohydrates

A
  • monosaccharides
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3
Q

Monosaccharides

A
  • units that can be joined together to form larger and more complex carbohydrates (polysaccharides)
  • General Formula: (CH2O)n
    -n: usually a number between 3-7
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4
Q

Glyceraldehyde

A
  • Simple example of a monosaccharide
  • One carbon is double bonded to an oxygen atom (carbonyl group)
  • each other carbon isbonded to an OH group (an alcohol group)
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5
Q

An Aldose

A
  • ex . glyceraldehyde
  • Carbonyl group is attatched to a terminal carbon
  • double bonded to an analdehyde group
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6
Q

A Ketose

A
  • carbonyl group is attatched to a center carbon (a ketone group)
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7
Q

Chiral Carbon

A
  • carbons with 4 different chemical groups bonded to them
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8
Q

Enantiomers

A
  • mirror images of eachother
  • same chemical groups
  • They cannot be superimposed on eachother (distinct molecules)
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9
Q

Hexoses

A
  • contains 6 carbons
  • They are all isomers of eachother (same chemical formula)
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10
Q

To Number the Carbons

A
  • start with the carbon closest to the carbonyl group
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11
Q

D-sugar

A
  • if the OH group on the highest chiral carbon is on the right
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12
Q

Epimers

A
  • monosaccharides that are isomers + differ only by the steveochemistry
    around one carbon
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13
Q

Cyclization

A
  • Anomeric carbon is attched to a oxygen
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14
Q

Haworth Projections

A
  • OH group on carbon 1 can be up or down - both equally legitiamite
  • If OH group is on the right of a fischer projection: will be down in Haworth
  • If OH group is on the left of a fischer projection: Will be up in Haworth
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15
Q

Anomeric Carbon

A
  • a configurations possible upon cyclization
  • always has 2 bonds to oxygen
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16
Q

Alpha Glucose

A
  • the OH group of carbon atom 1 is on the opposite side of carbon 6 substituent
17
Q

Beta Glucose

A
  • the OH group of carbon atom 1 is on the same side of carbon 6 substituent
18
Q

Disaccharides

A
  • monosaccharides can be joined in a condensation reaction
19
Q

Sugar

A
  • sucrose (common usage)
20
Q

Polysaccharides as Energy Storage

A
  1. Glycogen in Animals
  2. Starch in Plants
21
Q
  1. Glycogen in Animals
A
  • 12-14 glucoses
  • alpha (1-4) linkages
    carbon 1 of one atom and carbon 4 of another are in alpha positions
22
Q
  1. Starch in Plants
A
    1. amylose
    1. amylopectin
23
Q

Amylose

A
  • 20-30%
  • alpha (1-4)- polyglucose
  • very few branch points
24
Q

Amylopectin

A

-70-80%
- alpha (1-4)- polyglucose
- alpha (1-6) branches every 24-30 glucose monomers

25
Q

Humans

A
  • can easily digest glycogen and starch
26
Q

Cellulose

A
  • unbranched beta(1-4) polyglucose
  • humans cannot digest beta
27
Q

Pectin

A
  • unbranched alpha(1-4) polymer
  • mainly D-galacturonic acid
  • partially methylates
28
Q

Dietary Fibre

A
  • polysaccharides that humans digest poorly
29
Q

Oligosaccharides as Cell Coating

A
  • protect cells
  • make cells slippery
  • mediate cell-cell recognition