topic 6b: alkanes Flashcards

1
Q

general formula alkane

A

CnH2n+2

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2
Q

what is an alkane?

A

saturated hydrocarbon

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3
Q

alkane main use

A

fuels

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4
Q

how do u obtain alkane fuels

A

fractional distillation of crude oil

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5
Q

how does fractional distillation work

A
  • oil heated and passed into column
  • temperature of column DECREASES upwards
  • fractions condense at different heights according to boiling point
  • bp depends on size of molecule
  • larger molecule = stronger LF so higher boiling point
  • molecules of similar length condense together
  • small molecules condense at the low temps at the top
  • bigger molecules condense at high temps at the bottom
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6
Q

cracking

A

conversion of large hydrocarbons to smaller molecules by breakage of C-C bonds

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7
Q

reasons for cracking?

A
  • shorter C chains in higher demand than longer
  • more useful- eg alkenes used to make polymers. smaller alkanes for motor fuels (burn more efficiently)
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8
Q

reforming

A

processing of straight-chain hydrocarbons into
branched-chain alkanes and cyclic hydrocarbons for efficient combustion

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9
Q

purpose of reforming

A
  • branched and cyclic hydrocarbons burn more cleanly
  • give fuels a higher octane number
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10
Q

what is a fuel

A

releases heat energy when burnt

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11
Q

why are alkanes good fuels

A

combustion is highly exothermic

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12
Q

complete combustion alkane

A

co2+h2o

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13
Q

incomplete combustion alkanes

A
  • limited amount of oxygen
  • less energy per mole produced
  • CO(toxic) /C (c gives soot)
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14
Q

carbon monoxide

A
  • highly toxic
  • odourless
  • reduces the o2 carrying capacity of blood
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15
Q

carbon production problem

A

particulates in atmosphere

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16
Q

sulfur compounds from combustion

A
  • sulfur impurities in fuel
  • produces SO2 when burnt
  • acidic
  • dissolves in atmospheric water to produce acid rain
  • harful to aquatic life
17
Q

NOx compounds from combustion

A
  • high temp and spark in engine provides sufficient energy to break strong N2 bond, causing N2 and O2 to react
18
Q

NOx compounds problem

A
  • NO = toxic, forms smog
  • NO2 = acidic, forms acid rain
19
Q

CO2 problems

A

-greenhouse gas
-global warming
- traps IR radiation from earthand reflects it back to earth

20
Q

catalytic converters

A
  • remove CO, NOx and unburned hcs from the exhaust gases
  • turn them into CO2, N2, H2O
21
Q

remaining unburned hydrocarbons problem

A

Toxic

22
Q

fossil fuels

A
  • from crude oil
  • finite , non renewable
23
Q

advantages of alcohol and biodiesel as fuel alternatives

A
  • renewable
  • carbon neutral
  • less pollution
24
Q

disadvtantage of biofuels and ethanol as fuel alternative

A
  • less food crops grown
  • rainforests cut down to provide land
  • shortage of fertile soils
25
Q

how are the alcohol fuels produced

A

fermentation of sugars from plants

26
Q

how are the biodiesel fuels produced

A

reacting veg oils with alkali and methanol