topic 6 Flashcards

1
Q

What does the rate of a chemical reaction depend on (2)

A
  • the collision frequency of reacting particles. The more collisions there are the faster the reaction is
  • the energy transferred during a collision. Particles have to collide with enough energy for the collision to be successful
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2
Q

The more collisions there are ….

A

The faster the reaction is

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3
Q

What is the activation energy

A

The minimum amount of energy that particles need to react

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4
Q

Why do particles need activation energy

A

To break the bonds in the reactants and start the reaction

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5
Q

What is the rate of a reaction

A

How fast the reactants are changed into products

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6
Q

2 examples of slow reactions

A
  • rustling of iron

- chemical weathering- acid rain damaging limestone buildings

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7
Q

An example of moderate speed reaction

A

-metal magnesium reacting with an acid to produce a gentle stream of bubbles

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8
Q

How can you find the speed of a reaction

A

By recording the amount of product formed r the amount of reactant used up over time

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9
Q

What does the rate of reaction depend on (4)

A
  • temperature
  • concentration of a solution or the pressure of gas
  • surface area
  • presence of a catalyst
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10
Q

What does more collisions increase

A

It increases the rate of reaction

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11
Q

3 ways in how increasing the temperature increases the rate

A
  • when the temperature is increases, the particles all move faster
  • if they are moving faster, they are going to collide more frequently
  • the faster they move the more energy they have, so more of the collisions have enough energy to make the reaction happen
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12
Q

What does it mean if a solution is more concentrated

A

It means there are more particles knocking about in the same volume of water or other solvent

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13
Q

What happens when the pressure of gas is increased

A

It means the same number of particles occupies a smaller space- this makes collisions between the reactant particles more frequent

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14
Q

How can you increase the surface area of a volume

A

If one of the reactants is a solid, then breaking it up into smaller pieces will increase its surface area to volume ratio

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15
Q

How does increasing surface area increase rate

A

It means that for the same volume of the solid, the particles around it will have more area to work on so there will be collisions more frequently

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16
Q

What is a catalyst

A

A substance that speed up the rate of a reaction without being used up in a reaction itself

17
Q

What do catalysts do in a rate of reaction

A

They work by decreasing the activation energy needed for the reaction to occur. They do this by providing an alternative reaction pathway with a lower activation energy

18
Q

What are enzymes

A

Biological catalysts- hey catalyse reactions in living things

19
Q

What is “Le Chatelier’s Principle”

A

The idea that if you change the conditions of a reversible reaction at equilibrium, the system will try to counteract that change

20
Q

What can “Le Chatelier’s Principle” be used to predict

A

The effect of any changes you make to a reaction system

21
Q

What does it mean if the equilibrium lies to the right

A

The concentration of products is greater than that of the reactants

22
Q

What does it mean if the equilibrium lies to the left

A

The concentration of reactants is greater than that of the products

23
Q

What does the position of equilibrium depend on what conditions (3)

A
  • the temperature
  • pressure
  • concentration of the reactants and products
24
Q

if you decrease the temp of a system, what happens to the equilibrium

A

it moves in the exothermic direction to produce more heat- this means you get more products for the exothermic reaction and fewer products for the endothermic reaction

25
Q

what does changing the pressure have an affect on equilibrium involving …

A

gases only

26
Q

what happens to the equilibrium if you increase the pressure

A

the equilibrium tries to reduce it- it moves in the direction where there are fewer molecules of gas

27
Q

what happens to the equilibrium if you decrease the pressure

A

the equilibrium tries to increase it- it moves in the direction of where there are more molecules of gas

28
Q

when will a system no longer be at equilibrium

A

if you change the concentration of either the reactants or the products

29
Q

what happens to the system if you increase the concentration of the reactants

A

the system tries to decrease it by making more products

30
Q

what happens to the system if you decrease the concentration of products

A

the system tries to increase it again by reducing the amount of reactants

31
Q

what does it mean if a system is at equilibrium

A

both reactions are still happening, but there is no overall effect. This means that the concentration of reactants and products have reached a balance and won’t change

32
Q

how is equilibrium reached

A

equilibrium is only reached if the reversible reaction takes place in a ‘closed system’.

33
Q

what is a closed system

A

it means that none of the reactants or products can escape and nothing else can go in