Topic 4B Group 7 Flashcards

1
Q

What is the trend in melting temperatures down group 7?

A

increases down the group

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2
Q

Why do the melting temperatures of group 7 increase down the group?

A

there is an increase in the number of electrons so the strength of london forces increases

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3
Q

What is sublimation?

A

the transition of a substance directly from the solid phase to the gas phase without passing through the intermediate liquid phase

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4
Q

What 3 factors does electronegativity depend on?

A
  • nuclear charge- the bigger the nuclear charge, the higher the electronegativity
  • distance between the nucleus and bonding pair of electrons, the shorter the distance, the higher the electronegativity
  • the shielding effect of electrons in inner energy levels, the fewer energy levels, the higher the electronegativity
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5
Q

What is the trend of electronegativity down group 7?

A

decreases down the group (fluorine is the most electronegative)

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6
Q

What is the trend of reactivity down group 7?

A

decreases down the group

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7
Q

Why does the reactivity of group 7 decrease down the group?

A
  • halogens tend to react by gaining an electron to their p-shell, they’re oxidising agents
  • the atoms become larger as you go down the group, and the outer e- is further from the nucleus so less attraction to the positive nucleus
  • outer e- is more shielded by inner shells as you go down the group
  • this means that it is harder for the atom to attract electrons so reactivity decreases
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8
Q

What state is fluorine at room temperature?

A

gas

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9
Q

What is the state of chlorine at room temperature?

A

gas

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10
Q

What state is bromine at room temperature?

A

liquid

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11
Q

What state is iodine at room temperature?

A

solid

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12
Q

What colour is chlorine in water?

A

pale yellow-green

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13
Q

What colour is bromine in water?

A

yellow/orange

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14
Q

What colour is bromine in cyclohexane?

A

darker orange/red

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15
Q

What colour is iodine in water?

A

brown

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16
Q

What colour is iodine in cyclohexane?

A

purple or violet

17
Q

Give the generalisations of reactions between group 7 and group 1/2? i.e. which reactions most vigorous, product formed, type of reaction

A
  • reactions most vigorous between top of group 7 and bottom of group 1/2
  • products of the reactions are ionic salts- usually white
  • redox reactions in which the halogen acts as an oxidising agent
  • oxidation state of halogen from 0 to -1 and oxidation state of metal from 0 to +1 or +2 depending on group
18
Q

What is the equation for lithium and chlorine?

A

2Li + Cl2 –> 2LiCl

19
Q

What is the equation between barium and bromine?

A

Ba + Br2 –> BaBr2

20
Q

When a more reactive halogen displaces a less reactive halogen, what is this reaction called?

A

displacement reaction

21
Q

Which halogens displace other halogens?

A
  • chlorine displaces bromine and iodine
  • bromine displaces iodine but not chlorine
  • iodine displaces neither chlorine or iodine
22
Q

What type of reaction is the halogen-halide displacement reaction?

A

redox reaction

23
Q

Define disproportionation

A

the simultaneous oxidation and reduction of an element in a single reaction (where one element undergoes both oxidation and reduction at the same time)

24
Q

What reactions with chlorine are disproportionation?

A
  • chlorine with water
  • chlorine with cold alkali
  • chlorine with hot alkali
25
Q

What is formed when chlorine reacts with water?

A

-dissolves to form chlorine water
-some of the dissolved chlorine reacts to form a mixture of 2 acids:
hydrochloric acid (HCl)
chloric (I) acid (HClO or HOCl)

26
Q

Give the reaction and oxidation states when you mix chlorine with water

A

Cl2(g) + H2O(l) —> HCl(aq) + HClO(aq)

0 -1 +1

27
Q

What is the equation for the ionisation of chloric acid?

A

HClO(aq) + H2O(l) —> ClO-(aq) + H3O+(aq)

28
Q

Why is chlorine used for water treatment?

A

chlorate acid ionises to form chlorate ions which kill bacteria in the water

29
Q

What are the products of chlorine with cold dilute aqueous sodium hydroxide?

A

-sodium chloride
-sodium chlorate(I) =bleach
-water
(it forms the salts of the reaction between chlorine and water)

30
Q

Give the equation and oxidation states of chlorine with cold dilute aqueous sodium hydroxide

A

Cl2 + 2NaOH —> NaCl + NaClO + H2O

0 -1 +1

31
Q

What is produced when chlorine reacts with hot concentrated sodium hydroxide solution?

A
  • sodium chloride
  • sodium chlorate (V)
  • water
32
Q

Give the equation and oxidation states of chlorine reacting with hot concentrated sodium hydroxide solution

A

3Cl2 + 6NaOH —> 5NaCl + NaClO3 + 3H2O

33
Q

Out of the 3 halides, Cl-, Br- and I-, which can be oxidised by chlorine?

A

Br- and I-