Topic 4 - Introduction to Kinetics Flashcards
How does a chemical reaction occur?
When particles of substances collide and have energy equal to or greater than the activation energy of the reaction and the particle orientation must be correct
What`s activation energy?
The minimum energy that gaseous reactant molecules must possess to undergo a reaction.
What is a Maxwell-Boltzmann curve?
A plot of number of gaseous molecules against the energy they have
What does the area under the graph represent in an M-B curve?
The total number of molecules in the sample
What is rate of reaction?
A measure of the change in the concentration of a reactant or product with respect to time.
What`s the effect of temperature on rate of reaction?
- Increases rate of reaction
- Increases kinetic energy of reacting particles
- Which leads to an increase in the frequency of collisions and frequency of successful collisions.
How does a Maxwell-Boltzmann curve change at increased temperature?
Shifts to the right so that a greater proportion of molecules have energy equal to or greater than the activation energy.
What`s the effect of increasing pressure on rate of reaction?
- Increases rate of reaction
- Pushes the reacting particles closer together
- Leads to increase in frequency of collisions and frequency of successful collisions
What`s the effect of increasing temperature on rate of reaction?
- Increases rate of reaction
- Increases the number of reacting particles
- Leads to an increase in frequency of collisions and frequency of successful collisions
How does a catalyst work ?
By providing an alternative reaction route that has a lower activation energy.