Topic 1 - Atomic structure and the periodic table (2) Flashcards

1
Q

HISTORY OF THE ATOM:
What was the first model of the atom?
Who created it and when?

A

at the start of the 19th century, John Dalton described atoms as solid spheres and said that different spheres made up the different elements

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2
Q

HISTORY OF THE ATOM:
What did John Dalton say about the atom?

A

he described the atoms as solid spheres and said that different spheres made up the different elements

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3
Q

HISTORY OF THE ATOM:
What did JJ Thompson conclude from his experiments?
When did this happen?
What did he call his new model?

A
  • atoms weren’t solis spheres, he concluded from his measurements of charge and mass showed that an atom must contain even smaller, negatively charge particles - electrons.
  • 1897
  • the became the ‘plum pudding model’
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4
Q

HISTORY OF THE ATOM:
Who discvered electrons and when?

A

J J Thompson
1897

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5
Q

HISTORY OF THE ATOM:
Who proved the plum pudding model to be wrong?

A

Ernest Rutherford

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6
Q

HISTORY OF THE ATOM:
Who conducted the alpha particle scattering experiments and when?

A

1909
Ernest Rutherford and his student Ernest Marsden

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7
Q

HISTORY OF THE ATOM:
What did they do in the alpha particle scattering experiment?

A

fired positively charged alpha particles at a thin sheet of gold

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8
Q

HISTORY OF THE ATOM:
Using the plum pudding model, what was expected to happed during the alpha particle scattering experiment and why?

A
  • they were expecting the particles to pass stright through the sheet or be slightly deflected at most
  • because the positive charge of each atom was thought to be spread out through the ball of positive charge
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9
Q

HISTORY OF THE ATOM:
What happened during the alpha particle scattering experiment which meant the plum pudding model could not be right?

A

whilst most of the particles did go straight through the gold sheet, some were deflected more than expected, and a small number were deflected backwards

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10
Q

HISTORY OF THE ATOM:
What model of the atom did Rutherford come up with after the alpha particle experiment?

A

the nuclear model

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11
Q

HISTORY OF THE ATOM:
What issue was foung with the idea that a ‘cloud’ of electrons surrounded the nucleus as Rutherford described?

A

the electrons would be attracted to the nucleus which would cause the atom to collapse

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12
Q

HISTORY OF THE ATOM:
How was Niel’s Bohr’s nuclear model different to Rutherford’s

A
  • he suggested that the electrons were contained in shells
  • he proposed that electrons orbit the nucleus in fixed shells and aren’t anywhere inbetween
  • each shell is a fixed distance from the nucleus
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13
Q

HISTORY OF THE ATOM:
In what order were the subatomic particles discovered?

A

electron
proton
neutron

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14
Q

HISTORY OF THE ATOM:
Who discovered the proton?

A

Ernest Rutherford
(he showed that the nucleus cn be divided into smaller particles, which have the same charge as a hydrogen nucleus)

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15
Q

HISTORY OF THE ATOM:
When was the neutron discovered and who by?

A

1932 by James Chadwick

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16
Q

HISTORY OF THE ATOM:
What is the name of the model of the atom that we use today?

A

the nuclear model

17
Q

ELECTRONIC STRUCTURE:
What can shells also be called?

A

energy levels

18
Q

ELECTRONIC STRUCTURE:
What number of electrons can fit on each shell?

A

1st - 2
2nd - 8
3rd - 8

19
Q

ELECTRONIC STRUCTURE:
What will an atom do if it does not have a full ouer shell?

A

react to fill it

20
Q

ELECTRONIC STRUCTURE:
Atoms are unreactive when …

A

they have a full outer shell

21
Q

ELECTRONIC STRUCTURE:
Nitrogen’s atomic number is 7, what is it’s electronic structure?

22
Q

ELECTRONIC STRUCTURE
Magnesium has an atomic number of 12, what is it’s electronic structure?

23
Q

PERIODIC TABLE DEVELOPMENT:
What two ways COULD elements have been categorized by in the early 1800s?

A

1) physical and chemical properties
2) their atomic weight
(as they didn’t know about any of the subatiomic particles)

24
Q

PERIODIC TABLE DEVELOPMENT:
How were elements arranged in the early 1800s?
What were the issues with this?

A

By their atomic weight
not all elements had been discovered
so early periodic tables were incomplete and some elements were placed in the wrong group as their properties were not taken into account

25
PERIODIC TABLE DEVELOPMENT: What pettern was noticed when elements were placed in order of atomic weight?
a periodic pattern was noticed in the properties of the elements
26
PERIODIC TABLE DEVELOPMENT: What scientist left gaps and predicted new elements for the periodic table
Dmitri Mendeleev
27
PERIODIC TABLE DEVELOPMENT: In what year did Dmitri Mendeleev create his version of the periodic table?
1869
28
PERIODIC TABLE DEVELOPMENT: What 2 things did Mendeleev do to make his peridic table more accurate?
1) he left gaps to indicate the existence of undiscovered elements 2) took into account the properties of elements as well as their atomic weight
29
PERIODIC TABLE DEVELOPMENT: Why did Mendeleev use the properties of elements as well as their atomic weight? Give an example
so elements with similar properties remained in the same group for example, with Te and I - iodine actually has a smaller atomic weight but is placed after tellurium as it has similar properties to elements in that group
30
PERIODIC TABLE DEVELOPMENT: Why did Mendeleev leave gaps in his periodic table?
to make sure elements with similar properties stayed in the smae groups some of these gaps indicated the existence of undiscovered elements which allowed him to predict what their properties might be - when they were found they fitted the pattern and helped to confirm his ideas
31
PERIODIC TABLE DEVELOPMENT: Name an element Mendeleev accurately predicted the chemical and physical properties for?
an element he called ekasilicon, which we now know today as germanium
32
PERIODIC TABLE DEVELOPMENT: How did the discovery of isotopes confirm Mendeleev predictions?
- it showed that Mendeleev was correct not to place elements in strict order of atomic weight but also to take into account their properties. - isotopes of the same element have different masses but the same chemical propeties so occupy the same position on the periodic table