Thermodynamics and Engines Flashcards
What is the first law of thermodynamics?
Q=ΔU+W
- the energy transferred to a system through heating is equal to the sum of the increase in internal energy and the work done by the system
When is Q positive?
when energy is transferred to the system by heating
when is ΔU positive?
when there is an increase in temperature
when is W positive?
when work is done by the system
What is an Open system?
-e.g?
matter can go flow in and out the system
-aerosol can
what is a closed system?
-e.g?
no matter can enter or leave the system
-air inside a balloon
what is an ideal gas?
-perfectly elastic collisions between molecules
-no intermolecular forces
-no potential energy = internal energy is equal to the sum of the kinetic energies of all its particles
what is the ideal gas equation?
pV= nRT
what is the equation between pressure, volume and temperature?
p₁V₁/T₁ = p ₂V ₂/T ₂
What is an adiabatic process?
no heat leaves or enter the system
- Q=0
- ΔU=-W
what is the equation for an adiabatic process?
pVˠ=constant
what is an isothermal process?
the temperature of the system remains constant
-ΔU=0
- Q=W
what is the equation for an isothermal change?
pV=constant
what is a constant pressure change?
(isobaric)
the pressure of the system remains constant
what is the equation for a constant pressure change?
W=pΔV