Thermodynamics Flashcards

0
Q

What is a surrounding?

A

Everything outside the system.

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1
Q

What is a system?

A

The part of a system we want to study. A reaction mixture.

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2
Q

What is an open system?

A

A system that can exchange both energy and matter with the surrounding.

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3
Q

What is a closed system?

A

A system that can only exchange energy with the surrounding.

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4
Q

What is an isolated system?

A

A system that can exchange neither energy nor matter with the surrounding.

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5
Q

What is thermochemistry?

A

Study of energy changes as matter undergoes physical, chemical or nuclear transformations.

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6
Q

What is energy?

A

The ability to do work.

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7
Q

What is kinetic energy?

A

Energy due to motion.

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8
Q

What is potential energy?

A

Energy due to position or stored energy.

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9
Q

What is thermal energy?

A

Total potential and kinetic energy a sample of matter has.

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10
Q

What is temperature?

A

Measure of average kinetic energy.

When kinetic energy increase, the motion of particles increase and thus the temperature increases.

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11
Q

What is heat?

A

Energy transformed from one substance to another due to temperature difference between them.

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12
Q

What is heat represented by and measured in?

A

Q

Measured in joules or kilojoules.

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13
Q

What is the formula to calculate heat?

A

Q = mct

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14
Q

What is the law of conservation of energy?

A

Energy cannot be created or destroyed.

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15
Q

What is specific heat capacity?

A

Amount of heat required to raise the temperature of 1 gram of a substance by 1*C.

16
Q

What is specific heat capacity measured in?

A

J/g*C

KJ/g*C

17
Q

What is molar heat capacity?

A

Specific heat capacity X molar mass

18
Q

What is calorimetry?

A

The experimental technique used to obtain information to calculate heat.

19
Q

What is enthalpy?

A

The amount of energy gained or lost when reactants form products. Represented by

20
Q

What is molar enthalpy?

A

The amount of heat gained or lost per mole of a substance during a reaction formula.

21
Q

What is the formula for molar enthalpy? What are the units?

A

Delta H = q/n

KJ/mol

22
Q

What is an exothermic reaction?

A

When their is a loss of heat from the system to the surrounding. Temperature increases. Negative molar enthalpy

23
Q

What is an endothermic reaction?

A

A gain of heat energy from the surrounding to the system. Temperature decreases. Positive molar enthalpy

24
Q

Which process is bond making?

A

Exothermic

25
Q

Which process is bond breaking?

A

Endothermic

26
Q

What is Hess’ Law?

A

The sum of the enthalpies of the steps of a reaction will equal the enthalpy of the overall reaction.

27
Q

What is standard enthalpies of formation?

A

The amount of heat lost or gained when one mole of a substance is made from its elements in their standard state.