Thermodynamics 2 Flashcards

1
Q

Define heat capacity

A

The amount of heat required to raise the temp of an object or substance a given amount

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2
Q

Give the equation to calculate quantity of heat with Heat Capacity (C)

A

q = C x change in temp

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3
Q

Define molar heat capacity

A

The amount of heat required to raise the temp of 1 mol of a substance by 1 degrees C

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4
Q

Give the equation to calculate q with molar heat capacity.

A

q = (Cm) x (moles of substance) x change in temp

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5
Q

Define specific heat

A

The amount of heat required to raise the temperature of
1 g of a substance by 1 °C.

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6
Q

Give the equation to calculate q using specific heat

A

q = (specific heat) x (mass of substance) x ∆T

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7
Q

What is Hess’s law?

A

The overall enthalpy change for a reaction is equal to the sum of enthalpy changes for the individual steps in the reaction.

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8
Q

Give the equation for the haber process.

A

3H2(g) + N2(g) 2NH3(g)

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9
Q

Define standard enthalpy of formation

A

The heat change that results
when one mole of a compound is formed from its elements at a pressure of 1 atm in their STANDARD STATES

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10
Q

Define standard HEAT of formation.

A

The enthalpy change for the formation
of 1 mol of a substance in its standard state from its constituent elements in
their standard states.

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11
Q

What is the value of an element at its most stable form?

A

zero

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12
Q

Give the equation for the fermentation of glucose under standard conditions.

A

C6H12O6(s) ➞ 2 C2H5OH(l) + 2 CO2(g) ΔHo = -72 kJ

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13
Q

what kind of process is breaking bonds?

A

endothermic

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14
Q

What kind of process is making new bonds?

A

Exothermic

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15
Q

Define bond dissociation energy.

A

The amount of energy that must be supplied to break a chemical bond in an isolated molecule in the gaseous state and is thus the amount of energy released when the bond forms.

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16
Q

How to calculate bond enthalpies.

A

Reactants - products

17
Q

How to calculate standard reaction enthalpy?

A

ΔrHo = ΣνH o(products) - ΣνH o(reactants)

18
Q

What is meant by state function?

A

A function or property whose value depends only on the present state, or condition, of the system, not on the
path used to arrive at that state.

19
Q

Define enthalpy change.

A

The heat change in a reaction or process at constant pressure; ΔH= ΔE+ PΔV.

20
Q

Define entropy.

A

The amount of molecular randomness in a system.

21
Q

What are spontaneous processes favoured by?

A

favored by a decrease in H (negative ∆H).
favored by an increase in S (positive ∆S).

22
Q

What are non spontaneous processes favoured by?

A

favored by an increase in H (positive ∆H).
favored by a decrease in S (negative ∆S).

23
Q

How to calculate entropy change?

A

ΔS = Sfinal - Sinitial