Thermodynamics 1 Flashcards

1
Q

Define energy

A

The capacity to supply heat or do work

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2
Q

Define kinetic energy

A

The energy of motion

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3
Q

Define potential energy.

A

Stored potential energy

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4
Q

Define thermal energy.

A

The kinetic energy of molecular motion, measured by finding the temperature of an object.

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5
Q

Define heat.

A

The amount of thermal energy transferred from one
object to another as the result of a temperature difference between the two.

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6
Q

Define Law of Conservation of Energy

A

Energy cannot be created
or destroyed; it can only be converted from one form to
another.

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7
Q

What are isolated systems.

A

They can neither do work upon nor heat their surroundings.
This means that their internal energies cannot change

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7
Q

Describe the internal energy of an isolated system.

A

It is constant

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8
Q

Define an exothermic process.

A

a change (e.g. a chemical reaction) that
releases heat.
A release of heat corresponds to a decrease in enthalpy.

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9
Q

Define endothermic process.

A

a change (e.g. a chemical reaction) that
requires (or absorbs) heat.
An input of heat corresponds to an increase in enthalpy.

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10
Q

Define enthalpy.

A

The measurement of energy
in a thermodynamic
system.

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11
Q

Define an open system.

A

Can exchange both matter and energy with the surroundings.

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12
Q

Define a closed system.

A

Can exchange only energy with the surroundings.

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13
Q

Define isolated system.

A

Can exchange neither energy nor matter with its surroundings.

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14
Q

Define state function.

A

A function or property whose value depends
only on the present state, or condition, of the system, not on the path used to arrive at that state.

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15
Q

How to calculate work?

A

Force x Distance

16
Q

What is expansion work?

A

Work done as the result of a volume change in the system.

17
Q

How to calculate change in energy when the system contracts and the atmosphere works upon the system.

A

∆E = q + w
q = ∆E + P∆V
q = heat transferred, w = work = -P∆V
Constant Volume (∆V = 0): qV = ∆E
Constant Pressure:
qP = ∆E + P∆V

18
Q

How to calculate enthalpy change?

A

∆H = Hfinal - Hinitial = Hproducts - Hreactants

19
Q

Define delta H

A

heat given off or absorbed during a reaction at constant pressure

20
Q

How to convert energy to joules.

A

Use 1 L . atm = 101.3 J

21
Q

How to calculate work done?

A

w = -P ∆V

22
Q

Define thermodynamic standard state.

A

Most stable form of a substance at 1 atm pressure (po) and at a specified temperature, usually 25
°C; 1 M concentration for all substances in solution.

23
Q

Define Enthalpy of Fusion.

A

The amount of heat necessary to melt a
substance without changing its temperature.

24
Q

Define enthalpy of vaporisation.

A

The amount of heat required to vaporize
a substance without changing its temperature.

25
Q

Define enthalpy of Sublimation.

A

The amount of heat required to convert a
substance from a solid to a gas without going through a liquid phase.