Thermal properties of matter Flashcards
Define internal energy
Internal energy of a substance is the sum of kinetic energy due to random motion of particles and potential energy due to forces of attraction between particles
Define heat capacity
Heat capacity, C, is the amount of heat required to raise the temperature of a substance by 1K
Define specific heat capacity
Specific heat capacity, c, is the amount of heat required to raise the temperature of a unit mass of a substance by 1K
What are the 2 types of latent heat
- Latent heat of fusion
- Latent heat of vaporisation
Define latent heat
Latent heat is the energy released or absorbed to change the state of a substance at constant temperature
Describe melting in terms of particles
- Energy supplied to do work against forces of attraction between particles
- Particles have wider range of movement and average distance between particles increases
- Internal energy of substance increases
- Kinetic energy of substance remains the same, so temperature remains constant
Describe freezing in terms of particles
- Energy released to surroundings causes forces of attraction to reform around particles
- Average distance between particles decreases
- Internal energy of substance decreases
- Kinetic energy of substance remains the same, so temperature remains constant
Define specific latent heat of fusion
Specific latent heat of fusion is the amount of heat required/released to change a unit mass of a substance between solid and liquid states at constant temperature
Define specific latent heat of vaporisation
Specific latent heat of vaporisation is the amount of heat required/released to change a unit mass of a substance between solid and liquid states at constant temperature
Define evaporation
Evaporation is the process where a liquid changes to a gas without boiling
What are some differences between evaporation and boiling
- Boiling occurs at fixed temperature
- Boiling occurs throughout the liquid
- Bubbles formed during boiling
- Temperature remains constant during boiling
Describe how evaporation occurs
- Particles in liquid are always moving randomly at different speeds
- Particles at liquid surface can escape to atmosphere as long as they have sufficient kinetic energy to overcome attractive forces of other liquid particles and do work against atmospheric pressure
- Less energetic particles are left behind
- Average kinetic energy of liquid particles decreases
- Average liquid temperature decreases