Thermal properties of matter Flashcards

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1
Q

Define internal energy

A

Internal energy of a substance is the sum of kinetic energy due to random motion of particles and potential energy due to forces of attraction between particles

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2
Q

Define heat capacity

A

Heat capacity, C, is the amount of heat required to raise the temperature of a substance by 1K

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2
Q

Define specific heat capacity

A

Specific heat capacity, c, is the amount of heat required to raise the temperature of a unit mass of a substance by 1K

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3
Q

What are the 2 types of latent heat

A
  • Latent heat of fusion
  • Latent heat of vaporisation
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3
Q

Define latent heat

A

Latent heat is the energy released or absorbed to change the state of a substance at constant temperature

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4
Q

Describe melting in terms of particles

A
  • Energy supplied to do work against forces of attraction between particles
  • Particles have wider range of movement and average distance between particles increases
  • Internal energy of substance increases
  • Kinetic energy of substance remains the same, so temperature remains constant
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5
Q

Describe freezing in terms of particles

A
  • Energy released to surroundings causes forces of attraction to reform around particles
  • Average distance between particles decreases
  • Internal energy of substance decreases
  • Kinetic energy of substance remains the same, so temperature remains constant
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6
Q

Define specific latent heat of fusion

A

Specific latent heat of fusion is the amount of heat required/released to change a unit mass of a substance between solid and liquid states at constant temperature

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7
Q

Define specific latent heat of vaporisation

A

Specific latent heat of vaporisation is the amount of heat required/released to change a unit mass of a substance between solid and liquid states at constant temperature

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7
Q

Define evaporation

A

Evaporation is the process where a liquid changes to a gas without boiling

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8
Q

What are some differences between evaporation and boiling

A
  • Boiling occurs at fixed temperature
  • Boiling occurs throughout the liquid
  • Bubbles formed during boiling
  • Temperature remains constant during boiling
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8
Q

Describe how evaporation occurs

A
  • Particles in liquid are always moving randomly at different speeds
  • Particles at liquid surface can escape to atmosphere as long as they have sufficient kinetic energy to overcome attractive forces of other liquid particles and do work against atmospheric pressure
  • Less energetic particles are left behind
  • Average kinetic energy of liquid particles decreases
  • Average liquid temperature decreases
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