thermal analysis Flashcards
thermogravimetric analysis
thermoanalytic technique in which phy and chem properties of materials are measured as a func of increasing temp
TGA thermogram
plot of mass against temperature which gives qual and quant info abt substance under study
applications of TGA
1) chemical stability above an elevated temp
2) identification and purity det
3) decomposition mechanism
4) det of compsn of alloys and metals
5) amount of filler in a polymeric sample
Limitations of TGA
1) limited to study of physical, chemical changes that can be followed by mass change
2) cannot be used for the study of fusion, crystalline transitions, glass transition and crystalline temp, solid state reactions with no volatile products
Differential thermal analysis
thermoanalytic technique that can be used as a finger print for identification of materials
DTA thermogram
plot of delta T= Ts-Tr versus the reference temp Tr
Applications of DTA
1) identification
2) environmental studies
3) quality control
4) purity
5) generation of phase diagram and study of phase transitions