THEORIES OF EMULSIFICATION Flashcards
The emulsifying agents cause a reduction in the interfacial tension of the two immiscible liquids, which cause the liquid to break up into smaller drops which as spherical in-shape
Surface Tension Theory
The use of surface active (surfactant or wetting agents as emulsifiers & stabilizers lowers the interfacial tension of the two immiscible liquids, reducing the repellent force between the liquids & diminishing each liquids attraction for its own molecules
Surface Tension Theory
The surfactant forms monomolecular layers around the droplets of the internal phase
Oriented wedge theory
Assumes monomolecular layers of emulsifying agent curved around a droplet of the internal phase of the emulsion
Oriented wedge theory
The emulsifier forms an interface between the oil & water, surrounding the droplets of the internal phase as a thin layer of film adsorbed on the surface of the drops
Plastic or Interfacial Film Theory
Places the emulsifying agent at the interface between the oil & water, surrounding the droplets of the international phase as a thin layer film adsorbed on the surface of the drops.
Plastic or Interfacial Film Theory
The viscosity of the medium aids in the emulsification by the mechanical hindrance to coalesce the globules
Viscosity theory