the acid dissociation constant Ka Flashcards
how can the dissociation of any weak acid be shown?
HA (EQUI ARROW) H+ +A-
how is the acid dissociation constant calculated? units are?
Ka = [H+][A-] / [HA]
UNITS = MOLDM^-3
what type of acid is the ka expression written for mainly
weak acid
write Ka expression for ethanoic acid?
[H+][CH3COO-] / [CH3COOH] (all aq)
what are recorded Ka values usually standardised at?
room temp
what does Ka change with?
temp
what happens to the position of equilibrium the larger the Ka value is?
the further the equilibrium is to the right
larger Ka value =
- greater dissociation
- greater acid strength
how do you turn Ka into pKa? and vice versa fo weak acids?
pka = -log(ka)
ka = 10^-pka
list 4 weak acids and their formulas
nitrous acid =HNO2
methanoic acid= HCOOH
ethanoic acid
chloric (I) acid = HCLO
what happens to Ka and pka values the stronger the acid is?
- larger Ka
- smaller pka
what happens to Ka and pka values the weaker the acid is?
- smaller ka value
- larger pka value
are ka or pka values easier to use for comparison of strength of weak acids?
pka
what is the formula of sulphurous acid
H2SO3