module 3 - enthalpy changes Flashcards

1
Q
  • what is enthalpy?

- what’s the symbol for enthalpy?

A
  • a measure of the heat energy in a chemical system

- H

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2
Q

what can enthalpy sometimes be thought of as being?

A

the energy stored within bonds

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3
Q

how is enthalpy measured?

A

it can’t be measured, so enthalpy change is measured

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4
Q

what is enthalpy change?

A

the difference between the enthalpy of the products and the enthalpy of the reactants

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5
Q

what equation works out enthalpy change?

A

enthalpy of products —- enthalpy of reactants = enthalpy change

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6
Q

what is the system?

A

the reactants and products

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7
Q

what are the surroundings?

A

the apparatus , the lab and everything outside the system

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8
Q

what is the universe?

A

everything, including system and surroundings

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9
Q

how can enthalpy change be determined?

A

experimentally by measuring energy transfer between system and surroundings

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10
Q

what does activation energy act as in chemical reactions?

A

a barrier

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11
Q

what is activation energy?

A

the minimum energy required to start a reaction by the breaking of bonds

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12
Q

do reactions with small or large activation energies happen more rapidly? why?

A
  • small

- because the energy needed to break bonds is readily available from the surroundings

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13
Q

what’s the unit for enthalpy change?

A

kj mol ^-1

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14
Q

what are standard conditions for standard state?

A
  • 100 kpa

- 298k

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15
Q

what is the standard enthalpy change of reaction?

A

the enthalpy change that accompanies a reaction in the molar quantities shown in an equation under standard conditions, with all reactants and products in their standard states

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16
Q

what does the standard enthalpy change of reaction always refer to?

A
  • a stated equation

- value depends on the balancing numbers

17
Q

what happens to the enthalpy change of reaction if you double the balancing numbers in the chemical equation?

A

the enthalpy change value will double too

18
Q

what’s the standard enthalpy change of formation?

A

the enthalpy change that happens when 1 mole of a compound is formed from its elements under standard conditions with all reactants and products in their standard states

19
Q

what is the enthalpy change of formation for elements?

A

0 kj mol^-1

20
Q

what is the standard enthalpy change of combustion?

A

the enthalpy change when 1 mole of a substance reacts completely with oxygen under standard conditions with all reactants and products in their standard states

21
Q

what is the standard enthalpy change of neutralisation?

A

the energy change that accompanies the reaction of an acid by a base to form 1 mole of H2O under standard conditions with all reactants and products in their standard states

22
Q

what product is always formed in neutralisation reactions?

A

water

23
Q

what’s the same for all neutralisation reactions?

A

the value of the enthalpy change of neutralisation