Tests For SO3²- Flashcards

1
Q

SO3²- +HCl

A

SO2 + Cl‐

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2
Q

SO2+Cr2O7²-(orange) acidic medium,

A

Cr2(SO4)3 (green)+ SO4²- + H2O

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3
Q

How do you distinguish between SO2 and CO2?

A

Cr2O7²- test, CO2 doesnot react

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4
Q

SO2 + MnO4‐

A

Mn2+ + SO4²-

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5
Q

SO2 + Ca(OH)2 ppt and colour and what happens when the product is further treated with SO2, is the series od reactions applicable with Ba(OH)2 also?

A

CaSO3(white), Ca(HSO3)2 forms, yes

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6
Q

[Ag(SO3)]‐ + AgNO3, mention colour of ppt

A

Ag2SO3(white)

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7
Q

Ag2SO3 + SO3²-

A

[AgSO3]-

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8
Q

When SO3²- is treated with AgNO3 what forms first? Complex or ppt?

A

Complex forms first

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9
Q

Is Ag2SO3 soluble in dil HNO3 and aqueous ammonia ?

A

Yes, its soluble in both

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10
Q

What happens on boiling the solution of the complex salt [AgSO3]-

A

Metallic silver is precipitated

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11
Q

SO3²- + Pb(NO3)2(colourless) or PbCH3COO-, give ppt colour also

A

PbSO3(white)

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12
Q

Zn + SO3²- in acidic medium

A

Zn2+ + H2S + water

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13
Q

How is H2S liberated in the previous reaction?

A

H2 liberated reduces SO3²- to H2S

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14
Q

Zn + dil HNO3

A

N2O

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15
Q

How is N2O liberated here

A

H2 liberated reduces NO3- to N2O

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