Ni²+, Zn²+, Mn²+ Flashcards

1
Q

Ni²+ + NaOH mention colour too

A

Ni(OH)2 (green ppt)

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2
Q

Is Ni(OH)2 soluble in NaOH or aq NH3? What product does it give?

A

It is not soluble in NaOH but soluble in aq NH3 to give (Ni(NH3)6)²+ (deep blue)

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3
Q

Ni²+ + NH4OH

A

Ni(OH)2

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4
Q

Ni²+ + CN- mention colour too

A

Ni(CN)2 (green)

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5
Q

With excess CN- Ni(CN)2 gives [Ni(CN)4]²- which is a yellow solution , true or false?

A

True

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6
Q

Ni²+ DMG +NH⁴+ mention colour too

A

[Ni(DMG)2] (brown red or cherry red ppt)

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7
Q

Zn²+ H2S /NH4OH mention colour too

A

ZnS(white ppt)

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8
Q

ZnS + dilHCl

A

ZnCl2 + H2S

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9
Q

ZnCl2 + NaOH mention colour too

A

Zn(OH)2 (white)

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10
Q

Zn(OH)2 + excess NH4OH

A

[Zn(NH3)2]²+

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11
Q

K4[Fe(CN)6] + Zn²+ mention colour too, is the product soluble in NaOH , whats the product?

A

K2Zn3[Fe(CN)6]2 (white), in NaOH the product is : [Zn(OH)4]- + (Fe(CN)6)⁴-

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12
Q

Mn²+ NaOH mention colour too, what does it give in excess NaOH

A

Mn(OH)2 (white), in excess : MnO(OH)2 (brown)

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13
Q

Mn²+ + NH4OH , where does equilibrium go?

A

Mn(OH)2 + NH⁴+ but here equilibrium goes backward

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14
Q

Mn²+ + PbO2/S2O8²-/BiO3-

A

MnO4- + Pb²+/SO4²-/Bi³+

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