Hg2²+ Flashcards

1
Q

Hg2²+ + Cl-, ppt color, is the ppt soluble in dil acids? What is it soluble in?

A

Hg2Cl2(white), no, it is soluble in aqua regia

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2
Q

Hg2Cl2 + aqua regia(HNO3 + HCl), is the product soluble, does it dissociate?

A

HgCl2 + NO + water, here HgCl2 is soluble but doesnot dissociate

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3
Q

Hg2²+ + NaOH, ppt color

A

Hg2O(black)

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4
Q

Is Hg2O soluble in excess base? , does it dissolve in dil HNO3

A

No, yes

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5
Q

Hg2O heating

A

HgO(black) + Hg(ppt)

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6
Q

Hg2²+ + CrO4²- , ppt color

A

Hg2CrO4(red)

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7
Q

Hg2CrO4 + aq NaOH

A

Hg2O + CrO4²- + water

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8
Q

Hg2²+ + KI , ppt color

A

Hg2I2 ( green ppt)

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9
Q

Hg2I2 + excess I-

A

[HgI4]²- + Hg(ppt)

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10
Q

Hg2²+ + CO3²- , ppt colour

A

Hg2CO3(yellow)

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11
Q

Hg2²+ CN- , ppt colour

A

Hg2(CN)2(white)

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12
Q

What does Hg2(CN)2 disproportionate to give? Give colour of product

A

Hg(ppt) + Hg(CN)2(black)

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13
Q

Is Hg(CN)2 soluble in H2O, does it dissociate to form ions?

A

Soluble but doesnot dissociate

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14
Q

Can Hg2²+, Hg²+, Pb²+ form complex with excess KCN?

A

No they cannot

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15
Q

Hg2Cl2 + SnCl2 , ppt color

A

Hg(black) + SnCl4

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16
Q

Hg2²+ NH3 + NO3- , mention colour of products, what can this reaction be used for?

A

HgO.[Hg(NH3)(NO3)] (white ppt)+ Hg(black ppt)+ NH4+. It can be used to distinguish between Hg+ and Hg²+