Acid Radicals Grp 2 Tests For Cl‐ Flashcards

1
Q

NaCl+ H2SO4 heat

A

HCl+ Na2SO4

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2
Q

MnO2 HCl heat

A

MnCl2+ Cl2 +H2O

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3
Q

What is the colour of Cl2?

A

Greenish yellow

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4
Q

NaCl + AgNO3 mention ppt colour too

A

AgCl(white)

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5
Q

What does AgCl give on reaction with aq NH3

A

[Ag(NH3)2]+

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6
Q

Write the series of reactions in chromyl chloride test with ppt and solution colours

A

NaCl + K2Cr2O7 + Con H2SO4–(heat)—–>CrO2Cl2(red brown)——-(NaOH)——->Na2CrO4
(Yellow)
—(Pb(CH3COO-)2/H+——->PbCrO4
(Yellow ppt)

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7
Q

Do the chlorides of Hg show chromyl chloride test? If yes, why ? If not why?

A

They donot owing to their slight ionization

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8
Q

Does full conversion to CrO2Cl2 occur with chlorides of Pb, Ag, antimony and tin?

A

No only partial conversion occurs

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