Test 1 Flashcards
Vitalism is
The idea that organic compounds arise only in organisms, which was disproved when chemists synthesized these compounds.
Mechanism is
The view that all natural phenomena are governed by psychical and chemical laws.
Explain the importance of Miller’s experiment.
Miller’s classic experiment supports the idea that abiotic synthesis of organic compounds could have been a stage in the origin of life.
Urea
CO (NH2)2
Describe Hydrocarbons
HC are organic molecules consisting of only hydrogen and carbon. Many organic molecules such as fats have HC components and can undergo reactions that release a large amount of energy.
Isomers are
Compounds with the same molecular formula but different structures and properties
Structural isomers have
Different covalent arrangements of their atoms
Cod-Trans Isomers have
The same covalent bonds but differ in spatial arrangements
Enantiomers are
Isomers that are mirror images of each other. Enantiomers are important to the pharmaceutical industry. Two enantiomers of a drug may have different effects. Usually only one isomer is biologically active. Differing effects of enantiomers demonstrate that organisms are sensitive to even subtle variations in molecules.
Functional groups are
The components of organic molecules that are most commonly involved in chemical reactions. The number and arrangements of functional groups give each molecule its unique properties.
The seven functional groups are
Hydroxyl (OH), carbonyl(O), carbonyl (COOH), amino (NH2), Sulfhydryl (SH), phosphate (OPO3) and Methyl (CH3)
Hydroxyl Group
OH. Alcohols (I.e Ethanol). Polar as a result of e- spending more time near the electronegative O atom.
Carbonyl Group
CO. Ketones and Aldehydes, which both may be structural isomers as is the case with acetone and propanol.
Carboxyl Group
COOH. Carboxylic acids, or organic acids. Acts as an acid, can donate an H+ because the covalent bond between oxygen and hydrogen is so polar.
Amino Group
NH2. Amines. Acts as a base; can pick up an H+ from the surrounding solution. Found in cells in the ionized form with a charge of 1+.
Sulfhydryl Group
SH. Thiols. Cross linking of cysteines in hair proteins maintains the curliness or straightness of hair. Breaking and re-forming the cross-linking bonds changes the structure.
Phosphate Group
OPO3. Organic Phosphates. Contributes - charge to the molecule of which it is apart of. (2- when at the end of a molecule, 1- when located internally in the chain of phosphates). Molecules containing phosphate groups have the potential to react with water, releasing energy.
Methyl Group
CH3. Methylated compounds. Addition of a methyl Group to DNA, or molecules bound to DNA, affect the expression of genes. Addition of methyl Groups in male/female sex hormones affects their shape and function.
ATP is
The primary energy transferring molecule in the cell. ATP consists of an organic molecule Calle Adenosine attached to a string of three phosphate groups.
Monosaccharides are classified by
- The location of the Carbonyl Group (as Aldose or Ketose)
2. The number of carbons in the carbon skeleton.
A disaccharide is formed when
A dehydration reaction joins two molecules. This covalent bond is called a glycosidic linkage.
Polysaccharides have storage and structural roles. The structure and function of a polysaccharide are determined by
It’s sugar monomers and the position of glycosidic linkages.
Starch (Polysaccharide)
A storage polysaccharide in plants, consists entirely of glucose monomers. Plants store excess starch as granules within chloroplast and other plastids. The simplest form of starch is amylose.
Glycogen (Polysaccharide) is
A storage polysaccharide in animals. Humans and other vertebrates store glycogen mainly in liver and muscle cells.
The polysaccharide cellulose is
A major component of the tough wall of plant cells. Like starch, cellulose is a polymer of glucose but the glycosidic linkages differ based on two ring forms: alpha (helical) and beta (straight).
Chitin (Polysaccharide)
Is another structural polysaccharide and is found in the exoskeleton of Arthopods. Chitin also provides structural support for the cell walls of many fungi.
Lipids
Are the one class of large Bio-molecules that do not form polymers. Lipids are hydrophobic since they mostly consist of HC which form non-polar bonds. Lipids consist of fats, phospholipids, and steroids.
Fats are constructed from
Glycerol, a three carbon alcohol with a hydroxyl Group attached to each carbon, and fatty acids, which consist of a carboxyl Group attached to a long carbon skeleton.
In a fat, 3 fatty acids are joined to glycerol by an
Ester linkage, creating a triaclyglycerol, or triglyceride.
Most animal fats are
Saturated