Technical challenges : part 6 / 7 : lipids Flashcards

1
Q

what are the function of lipid ingredients ?

A
  1. lubricant and tenderizer 2. heat exchange medium 3. carriers of fat soluble vitamins 4. textual ingreidents of emulsions 5. contribute to mouthfeel and flavor 6. emulsifier and surfactant
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2
Q

what is the difference between surfactant and emulsifier

A

emulsifier : will form the emulsion surfactant: will stabilize the emulsion and form the emulsion

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3
Q

what are the 6 properties to which we need to be carfull when selecting the appropriate lipid ingredient

A

1-nutrtional profile 2- flavor profile 3- crystallization behavior 4- oxidtive stability 5- bulk physicochemical properties 6- oil quality

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4
Q

*what are the two ways lipids can contribute to the flavor of a food

A

directly indirectly

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5
Q

What is the directly way that a lipid can contribute to the flavor of a food

A

by having flavor components inside the oil that will give a flavor to the food

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6
Q

What is the indirect way that a lipid can contribute to the flavor of a food

A

the chosen oil will affect the solubility and availability of the flavours inside the food it is added to

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7
Q

the melting point will increase with the ___ and ___

A

chain length and the saturation.

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8
Q

in lipids, the liquid to solid transition is called ____

A

crystallization

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9
Q

what is the crystal form with the best textural properties

A

beta prime

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10
Q

What are the factors that will influence the morphology of crystals?

A

1- internal factors (molecular structure, composition and interaction) 2- external factors (temperautre-time profile, agitation and impurities)

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11
Q

large crystals are ___ in the mouth

A

grainy

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12
Q

small crystals cause ___ sensation in the mouth

A

cooling

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13
Q

if the temperautre is decreasing rapidly, the crystals will be more ____

A

grainy

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14
Q

what are the factors that influence the oxidation of lipids

A

1- metals 2- oxygen 3- presence of light

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15
Q

what are the three caracteristics that lipids must have in order to enhance the formation and stability of emulsions

A

1- rapidly absorb to the surface of the freshly formed emulsion dropplets 2- must reduce the interfacial tension 3- must form an interfacial layer that prevent the aggregation of droplets

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16
Q

t or f : if you don’t reacht he critical concentration, you won’t have emulsifying properties

A

true

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17
Q

true or false : both the emulsifier and the surfactant will reduce the surface tension between the two phases

A

true

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18
Q

what are the 4 ways to stabilize an emulsion

A

1- electrostatic stabilization 2- steric stabilization 3- particle stabilization 4- multilayer stabilization

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19
Q

how is measured the surface activity ?

A

the ratio of hydropilic to lipophilic groups = hydrophile - lipophile blanance HLB

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20
Q

what is the formula HLB ?

A

HLB = 7 + total(hydrohilic group number) - total(lipophilic group numbers)

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21
Q

when the HLB is between 10-12, the emulsifier is hydrophilic or hydrophobic?

A

hydrophilic

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22
Q

when the HLB is between 3-5, the emulsifier is hydrophilic or hydrophobic?

A

hydrophobic

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23
Q

if the HLB is between 7-9, how are the surface activity properties

A

very high but there will be coalescence

24
Q

What are the drawbacks of the HLB?

A

1- don’t take into acount the functional properties of the surfactant in various environments 2- the HLB depends on the oil type 3- no information on the type or amount of surfactant

25
T or f : the surface activity of the monomers is always higher than the surface activity of the micelles
false it depends
26
Each surfactant will organize in different ways depending on :
1- chemical structure of the surfactant 2- interactions of the surfactant molecule 3- nature of the continuous phase 4- temperautre
27
What is the critical micelle concentration?
the concentration at which there is micelle formation
28
In which case would you want to be over the critical micelle concentration
when you want to be able to disperse/ encapsulate hydrophobic flavors
29
What happens below the critical concentration
the monomers will aggregate into monomers
30
When you have ____ ionic strenght, you will have a higher CMC. Explain
high. because the electrostatic repulsion between the micelles formation decrease the micelle formation
31
True or false : you will get more micelle formation when you have a surfactant that is more hydrophobic
true
32
The CMC decreases when the hydrophobicity \_\_\_
decreases
33
\*\*\*\* when you increase the concentration over the CMC the micelle size will \_\_\_\_
stay constant, it is the number of micelles that will increase
34
T or F : the shape and size of the micelles will never change because of the CMC
true
35
What is the packing parameter p
a parameter that will give the type of association we will have between the monomers
36
what is the phase inversion temperature
a temperature at which you will have inversion of the micelles
37
What is the kraft point
it is a point at which the solubility of the monomers is equal to the solubility od the micelles.
38
What is the bancroft's rule
a rule that states that the phase in which the surfactant is most soluble will form the continuous phase of the emulsion.
39
a water soluble surfactant should stabilize ____ emulsions
oil in water
40
an oil soluble surfactant should stabilize a ____ emulsions
water in oil
41
what is the cloud point ?
a temperautre at which we start having cloudness in a product
42
\*\*\* exam : what are the three categories of products used to reduce the caloric content of fat in foods
1- fat mimetic or replacement 2- fat extender 3- fat substitutes
43
\*\*\*exam : what is a fat mimetic?
it is a non-fatty substance that can replace some of the fat properties.
44
\*\* exam : what is a fat extender ?
it is a system ingredients used in combination with standard fats to acheive reduction of fat
45
\*\* exam : what is a fat substitute ?
it is a fat that can't be digested by the lipases so it doesn't provide as much calories as regular fat
46
what are the 4 mechanisms by which fat mimetic ingredients act to provide fat texture?
1. entaglement 2. network gels 3. particle gels 4. particle gel aggregates
47
what are entanglement
it is a mechanism by which there is a fat mimetic because of the production of a slippery texture and viscosity
48
what are netwrok gels
it is a mechanisms by which there is fat mimetic by the porduction of a gel
49
what are particle gels
it is a mechanisms by which there is the production of a fat mimetic property because of the small particles that will self assemble to mimic a gel
50
what is the difference between the particle gels and the particle gel aggregates in the fat mimetic mechnanisms
in the case of the particle gels, it is non-continuous while in the case of the particle gel aggregate it is continuous
51
what are the fat substitutes seen in class ?
1. esterified propoxylated glycerol (EPG) 2. FA partially esterified polysaccharide (PEP) 3. Carbohydrate FA ester (CFAEs) 4. Sucrose polyester (SPE) 5. alkyl glycoside FA esters
52
What are EPG ?
fat subsitute in which FA that are esterified with propylene oxide
53
what is PEP
FA partially esterified polysaccharide. The polysaccharide is esterified with a fatty accid
54
What are carbohydrate fatty acid esters ?
carbohydrate that are esterified with fatty acids. one example would be sucrose fatty acid esters. They are non digestible
55
Are PEP digestible ?
non digestible and non absorbable
56
Are EPG digestible?
yes, slightly
57