synthetic routes jessie u just have to learn these Flashcards

1
Q

alkane to haloalkane

A

free radical substitution

halogen X2 and UV radiation

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2
Q

haloalkane to alcohol

A

nucleophilic substitution
NaOH and heat
(also forms NaX)

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3
Q

alcohol to aldehyde

A

K2Cr2O7 and H2SO4 (acid catalyst)
distill
primary alcohol

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4
Q

aldehyde to carboxylic acid

A

K2Cr2O7 and H2SO4 (acid catalyst)

under reflux

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5
Q

alcohol to carboxylic acid

A

primary alcohol
K2Cr2O7 and H2SO4 (acid catalyst)
under reflux

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6
Q

alcohol to haloalkane

A

halide with acid catalyst (conc. H2SO4)

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7
Q

alcohol to alkene

A

heat, acid catalyst (H3PO4)

also forms water

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8
Q

alcohol to ketone

A

secondary alcohol
K2Cr2O7 and H2SO4 (acid catalyst)
under reflux

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9
Q

alkene to dihaloalkane

A

addition

X2 (eg. Br2)

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10
Q

alkene to alkane

A

H2 and Ni catalyst

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11
Q

alkene to haloalkane

A

addition

XH

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12
Q

alkene to alcohol

A
steam 
acid catalyst (H3PO4)
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13
Q

haloalkane to alcohol

A

NaOH and heat

also form water

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14
Q

haloalkane to primary amine

A

react with excess ethanolic ammonia

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15
Q

haloalkane to secondary amine

A

primary amine

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16
Q

haloalkane to nitrile

A

KCN and ethanol (ethanol is just a condition)

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17
Q

aldehyde to alcohol

A

NaBH4 (reduction)

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18
Q

aldehyde to hydroxynitirles

A

acidified cyaninde ions

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19
Q

ketone to alcohol

A

NaBH4 (reduction)

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20
Q

ketone to hydroxynitriles

A

acidified cyanide ions

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21
Q

carboxylic acid to ester

A

alcohol and H2SO4

22
Q

carboxylic acid to acyl chlorides

23
Q

carboxylic acid to amides

24
Q

ester to alcohol

A

hydrolysis with heat and acid

also forms carboxylic acid

25
ester to carboxylic acid
hydrolysis with acid and heat | also forms alcohol
26
ester to carboxylate salts
hydrolysis with heat and alkali | also forms alcohol
27
ester to alcohols (2)
hydrolysis with heat and alkali | also forms carboxylate salts
28
acyl chlorides to ester
alcohol/phenol
29
acyl chlorides to carboxylic acid
water
30
acyl chloride to primary amide
ammonia
31
acyl cholride to seconodary amide
primary amine
32
amines to amine salts
react with acids
33
amines to amides
acyl chlorides/carboxylic acids
34
amides to amine salt
heat plus acid hydrolysis | carboxylic acid is also made
35
amides to carboxylic acid
heat plus acid hydrolysis | amine salt is also made
36
amides to caboxylate salts
heat plus alkali hydrolysis | amines is also made
37
amides to amines
heat plus alkali hydrolysis | carboxylate salt is also made
38
nitriles to amines
H2 with Ni catalyst
39
nitriles to ammonium salt
acid hydrolysis | also makes carboxylic acids
40
nitriles to carboxylic acids
acid hydrolysis | also makes ammonium salt
41
alcohol to ester
carboxylic acid and conc. H2SO4
42
benzene to nitrobenzene
conc. HNO3 conc. H2SO4
43
benzene to halobenzene
halogen and FeCl3
44
benzene to extended carbon chain
haloalkane or acly chloride with AlCl3 halogen carrier
45
phenol to salt
NaOH
46
phenol to ester
acyl chloride
47
phenol to bromophenol
bromine (no catalyst)electrophilic substitution
48
phenol to 2-nitrophenol
electrophilic substitution nitric acid (dilute)
49
phenol substitutes in
2 4 6
50
phenylamine substitues in
2 4 6
51
nitrobenzene to phenyl amine
tin and conc HCL | makes water als0
52
nitrobenzene substitues
3 5