key words Flashcards
relative isotopic mass
the mass of an atom compared to 1/12th the mass of carbon 12`
relative atomic mass
the weighted mean mass of an atom compared to 1/12th the mass of carbon 12
isotopes
atoms of an element with the same number of protons but different number of neutrons
molar mass
mass per mole
units of molar mass?
g/mol
mole
the unit of amount of substance 6.02 x 10^23 is one mole
acid
releases H+ ions in an aqueous solution
strong acid
fully dissociates in solution
weak acid
partially dissociates in solution
alkali
a soluble base that releases OH- ions in an aqueous solution
orbital
an area in space, around the nucleus where you can find up to two electrons with opposite spin
disproportionation
oxidation and reduction of the same element
1st ionisation energy
the energy required to remove one mole of e- from one mole of an element in a gaseous state
ionic bonding
the electrostatic attraction between oppositley charged ions
covalent bonding
strong electrostatic attraction between a shared pair of electrons and the nuclei of the bonded atoms
polar molecule
a molecule with polar bonds that is asymmetrical and the polar bonds do not cancel out
metallic bonding
the electrostatic attraction between positively charged metal ions and the sea of delocalised electrons
electronegativity
the ability of an atom to attract the shared pair of electrons in the covalent bond to itself
standard states
physical states under standard conditions
standard conditions
pressure; 100kPa
temp: 298K
enthalpy change of formation
the enthalpy change when one mole of a compound is formed from its elements in their standard states in standard conditions
enthalpy change of combustion
the enthalpy change for the complete combustion of one mole of a substance in standard conditions
enthalpy change of neutralisation
the enthalpy change for the formation of one mole of water from a neutralistation reaction in standard conditions
activation energy
the minimum energy required for a reaction to take place
homologous series
a series of organic compounds having the same functional group and each successive member differing by CH2
structural isomers
compounds with the same molecular formula but different structural formula
homolytic fission
breaking a covelent bond to form two radicals, both of them taking one electron
heterolytic fission
breaking a covelent bond to form two oppositely charged ions
E/Z isomerism
an example of stereoisomerism, due to a restricted rotation about a double bond, and two different groups attached to each carbon atom of the C=C group
Cis-Trans isomerism
a special case of E/Z isomerism in which two of the subsiquent groups attatched to each carbon of the C=C group are the same
electrophile
electron pair acceptor
nucleophile
electron pair donator
homogenous catalyst
a catalyst in the same state as the reactants (ususally in solutions)
heterogenous catalyst
a catalyst in a different state to the reactants
dynamic equilibrium
when the rate of the forward reaction is equal to the rate of the reverse reaction; the concentration of products and reactants do not change; in a closed system
catalyst
chemical that increases the rate of both forward and reverse reactions equally in an equilibrium reaction resulting in an unchanged position of equilibrium
sigma bond
σ-bond
overlap of orbitals directly between the bonding atoms
pi bond
π-bond
sideways overlap of adjacent p-orbitals above and below the bonding atoms
stereo isomers
compounds with the same structural arrangement but a different arrangement in space
curly arrow
shows the movement of a pair of electrons during a reaction
brady’s reagent
reacts with aldehydes and ketones to form an orange precipitate
tollens reagent
reacts with aldehydes only and forms a silver mirror
bronsted lowry base
proton acceptors
bronsted lowry acid
proton donator
isoelectric point
the ph where an amino acid can reach its zwitter ion, the overall change is neutral
optical isomers
non superimposable images of each other
enatiomers
optical isomers of each other
racemic mixture
50 50 split of two enatiomers
chiral centers
carbon with four groups attatched
polymerisation
process in which monomeres are joined togerth to make larger molecules consisting of repeating units
addition polymerisation
c=c bonds
condensation polymerisation
polyesters polyamides
carbon environment
tells you the position of a carbon molecule in a compound