Structure of Composites Flashcards
Define Composite
two or more materials put together, with each contributing to the overall properties
Disadvantages of Silicate Cements - 3
- Cannot be used for permanent tooth erosion in a few years
- Soluble in oral fluids
- Discolouration
Advantages of PMMA - 4
- Tooth like appearance
- Insoluble in oral fluids
- Easy to manipulate
- Low Cost
Disadvantages of PMMA - 4
- High setting shrinkage (causes secondary caries)
- Poor wear resistance
- Different coefficient of thermal expansion to tooth
- Problems with reduced inclusion of quartz powder as filler
What type of composite is currently used?
Resin Based Direct Composite filling material
What are the 3 Phases of Dental Composites
- Organic Matrix
- Inorganic Filler
- Bonding Agent
Why is Bis-GMA used instead of MMA in composite fillings?
MMA has a lower molecular weight -> more volume shrinkage of the material after polymerisation
Where does the Free Radical Substitution take place?
In the C=C double bond in the methacrylates.
What are the other additives in the Organic Matrix?
- Hydroquinone
- DHPT ( Activator for RTP Cure and LIGHT CURE)
- Camphorquinone (LC)
- Filler
- Iron oxide (pigment)
- UV stabilisers
- Optical Brighteners
How do direct composite fillings work?
Placed in the unset state and then is cured (set) in the oral cavity
What is the role of the organic matrix in a dental composite?
It is the plastic resin that polymerises to form a continuous phase
What is the role of the coupling agent in a dental composite?
To promote adhesion between filler and matrix resin
What monomer does the organic matrix consist of?
Bis-GMA
What is Bis-GMA prepared from?
Bisphenol A
Glycidyl Methacrylate
Viscosity of Bis-GMA
700,000cps