Composites: Bonding to Dentine Flashcards

1
Q

Is tooth tissue hydrophobic or hydrophilic?

A

Hydrophilic

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2
Q

Are most restorative materials hydrophobic or hydrophilic?

A

Hydrophobic

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3
Q

What adhesive bonds can occur between tooth tissue and restorative material? 3

A
  • Micromechanical
  • Molecular Entanglement
  • Chemical
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4
Q

Which bond needs to be achieved for longevity between tooth tissue and restorative material?

A

Chemical bond

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5
Q

What are 5 advantages of adhesives?

A
  • Better aesthetics
  • Conservation of tooth tissue
  • Reinforcement of weak tooth structure
  • Reduced marginal leakage
  • Reduced potential for pulp sensitivity
  • Range of techniques
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6
Q

What are the 5 ideal requirements for adhesives?

A
  • Provide high bond strength to enamel and dentine
  • Immediate and durable bond
  • Prevent ingress of bacteria
  • Safe to use
  • Simple to use
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7
Q

Composition ENAMEL structure by weight

Mineral
Organic material
Water

A

96% Mineral

1% Organic material

3% Water

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8
Q

When would you need to bond a restoration to enamel? 2

A
  • Orthodontic appliances

- Bridges

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9
Q

Comment on the surface tension of enamel compared to the adhesive resin

A
  • Surface tension of enamel is lower
  • So perfect wetting cannot take place
  • (Resin won’t flow/cover the enamel surface properly)
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10
Q

What layer covers enamel?

A

Pellicle Layer

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11
Q

How can adhesion onto an enamel surface be achieved?

A
  • Pellicle layer of enamel must be removed

- Enamel surface must be etched to raise surface tension

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12
Q

How is the pellicle layer removed and enamel etched?

A

Acid etch technique

- Involves using 30-50% PHOSPHORIC acid on the enamel surface

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13
Q

What are the 4 main effects of the acid etch technique?

A
  • INCREASED surface roughness
  • Surface energy is RAISED
  • IMPROVED wet-ability
  • Opens inner prism area for interlocking tag formation
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14
Q

What visible appearance is present when adequate etching has been achieved?

A

Enamel has a ‘FROSTY’ appearance

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15
Q

What is recommended to apply after an acid etching?

A

Low viscosity resin before placing composite

E.g. Unfilled Bis-GMA or dentine adhesive resin

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16
Q

Name 6 dental procedures where the acid-etched enamel is used for

A
  • Fissure sealing
  • Direct Composite
  • Ceramic Veneers
  • Resin Bonded bridges
  • Orthodontic brackets
  • Periodontal splinting
17
Q

Why does a restorative resin have to be adhesively bonded to dentine?

A
  • Retain restoration in the cavity

- Removed marginal gaps to stop bacterial microleakage

18
Q

Composition of DENTINE structure by weight

Inorganic Hydroxyapatite
Organic Material
Water

A

70% Inorganic HA

20% Organic Material (Hydrated Collagen)

10% Water

19
Q

What 2 things happens when dentine is cut?

A
  • Fluid is pumped through the dentine tubules giving a wet surface
  • Inorganic HA crystals are broken up, collagen stretched, torn and smeared over the cut surface
20
Q

What is the organic material of dentine mainly composed of?

A

Hydrated Collagen

21
Q

What are the 3 essential components of a dentine bonding agent?

A
  • Conditioner
  • Coupling agent
  • Sealer
22
Q

What is the role of the conditioner in a dentine bonding agent?

A

Acidic so modifies/clears smear layer

23
Q

What is the role of the coupling agent in a dentine bonding agent?

What molecule does it contain?

A

Used as a adhesive

Hydroxyethyl Methacrylate

(HEMA)

24
Q

What is the role of the sealer in the dentine bonding agent?

What agents can be used as sealers?

A

Seals the Dentine Tubules

Unfilled Bis-GMA or UDMA

25
The interpenetrating layer of dentine and resin is referred to as?
The hybrid zone
26
What are the 2 bonds found in dentine adhesion?
- Micro-mechanical | - Entanglement
27
Explain the bonding between the dentine tubules and coupling agent
Molecular entanglement with OH groups of primer
28
Explain the bonding between coupling agent and the sealer
Methacrylate group of coupling chemically bonds to methacrylate group of sealer
29
Explain the bonding between the sealer and filled-composite material
Methacrylate group of sealer chemically bonds to methacrylate group on filled composite material
30
What will happen if there is excessive desiccation of dentine?
Post operative pulpal sensitivity and a poor bond
31
If there is bond failure amongst dentine adhesion what may occur?
Pulpal inflammation leading to bacterial leakage
32
What are 4 potential causes for adhesive bond breakdown?
- Polymerisation shrinkage - Differential thermal expansion and contraction - Internal stresses for occlusal loading - Chemical Attack (Hydrolysis)