Skin care Flashcards

1
Q

what is ultraviolet radiation?

A

a high-energy form of light present in sunlight

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2
Q

UV-A

A

longest wavelength and is not absorbed by the ozone

penetrates the skin deeper than UV-B

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3
Q

UV-B

A

responsible for sunburns

partially blocked by the ozone layer

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4
Q

UV-C

A

totally absorbed by Earth’s atmosphere

we encounter it only from artificial radiation sources

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5
Q

what can exposure to UV light result in?

A

molecules gaining enough energy for bonds to be broken.

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6
Q

UV damage

A

because UV has enough energy to break chemical bonds, over-exposure can lead to the breakdown of important organic molecules within our body

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7
Q

what do UV-A and UV-B cause?

A

UV-A - sunburn
UV-B - skin ageing
both can cause skin cancer

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8
Q

sunburn

A
  • skin becomes inflamed and red in response to overexposure to UV (typically UV-B)
  • skin may peel to get rid of any damaged cells
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9
Q

photoaging

A
  • UV-A and UB-B exposure cause the collagen in the skin to breakdown.
  • As the skin attempts to repair itself it does so imperfectly and solar scars form. This forms wrinkles.
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10
Q

skin cancer

A
  • UV light can damage DNA cells and stop them from functioning correctly
  • These mutations to the genetic material can cause cancerous growths seen in skin cancer
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11
Q

sunscreen

A
  • contain compounds that filter the UV light so that less UV reaches the skin
  • contain organic compounds which absorb the UV light and dissipate the energy as heat before it can penetrate into your skin and damage cells.
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12
Q

sunblocks

A
  • contain compounds that reflect the UV light so it does not reach the skin at all
  • contain inorganic compounds like zinc oxide or titanium dioxide
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13
Q

what happens when UV light breaks bonds

A

free radicals are formed

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14
Q

what are free radicals

A

the atoms formed which have unpaired electrons and, as a result, are highly reactive

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15
Q

free radical reactions

A

-UV light has enough energy to break apart a covalent bond forming two atoms with unpaired electrons

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16
Q

free radical chain reaction

A

free radicals are unstable due to unpaired e- and so react very quickly with any other chemical nearby to form new bonds.

17
Q

3 steps in free radical chain reactions

A
  1. initiation
  2. propagation
  3. termination
18
Q

Initiation

A

the UV light causes some of the Cl-Cl bonds to break

2 free radicals on the RHS

19
Q

Propagation

A

highly reactive free radicals react with hydrogen molecules forming H-Cl and a hydrogen radical which can react with chlorine molecules
1 free radical on each side

20
Q

Termination

A

The free radicals react with other radicals to form stable substances. This terminates (stops) the process
2 free radicals on LHS

21
Q

reactions of alkanes with halogens

A

alkanes will decolourise bromine when UV light is present in free radical reactions

22
Q

what are free radical scavengers?

A

molecules that can react with free radicals to form stable molecules and prevent chain reactions

23
Q

what are free radical scavengers added to?

A
  1. cosmetics (eg: anti ageing creams, vit. C/E
  2. food products (eg: antioxidants, slow down oxidation)
  3. plastics
24
Q

examples of natural free radical scavengers

A

melatonin and vitamin E