Silicate-bonded MgO refractories Flashcards
How are silicate bonded MgO refractories made?
> bricks are PRESSED from DEAD BURNED MgO + sulphate LYE BINDER, fired in a tunnel kiln at 1500-1900C for 3-5 days
What are typical impurities in silicate bonded MgO refractories?
> CaO and SiO2
local equilibrias are established between CaO/SiO2 and the MgO clinker
What ratio of CaO/SiO2 impurities facilitates formation of lots of low-temp liquid phase?
1:1
What are the applications for silicate bonded MgO refractories?
> limited usefulness as a refractory, used in CHECKERWORK in a GLASS TANK REGENERATOR (heat exchanger)
What ratio of CaO/SiO2 impurities results in eutectic liquid forming only at higher temps?
2:1
What happens as CaO/SiO2 –> 0?
> refractory phases again results
Why must B2O3 impurities be avoided?
> it fluxes the Ca2SiO4 phase, and the refractory will float apart at ~1200C