Shapes Of Molecules And Ions Flashcards
What is electron pair repulsion theory?
The shape depends on the number of electron pairs around the central atom
Electron pairs repel each other so stay as far away as possible
What is the shape with 4 bond pairs called and what is the bond angle?
109.5
Tetrahedral
What is the shape with 5 bond pairs called and what is the bond angle?
120, 90
Trigonial bipyramidal
What is the shape with 6 bond pairs called and what is the bond angle?
90
Octahedral
What is the shape with 3 bond pairs called and what is the bond angle?
120
Trigonial planar
What is the shape with 2 bond pairs called and what is the bond angle?
180
Linear
How does the repulsing between lone pairs and bonding pairs vary?
Greater as the electron pair is closer to the nucleus, reducing the bond angle by 2.5° each time
What is the structure of an ionic compound?
The arrangement of ions in the lattice which maximises the attractive forces between oppositely charged ions and minimises repulsive forces
They attract opposite be charged ions in all directions and therefore repel them similarly
What are allotropes?
Different forms of the same element that exist in the same physical state. This depends on the bonding between the atoms
What is the structure of diamond?
Interlocking tetrahedral carbon atoms, each covalently bonded to 4 others in a giant molecule
What is the structure of graphite?
Planes of trigonal carbon atoms, each bonded to 3 other atoms at 120°
These planes are arranged in sheets to phone 3-D crystals, held together by weak intermolecular forces between the layers
Why can carbon conduct electricity?
Each atom has only three covalent bonds so the remaining outershell electrons is free to circulate within each plane of the atoms
What is the most reactive form of carbon?
Amorphous
Burns quite easily in there and attacked by strong oxidising agents
What does the properties of amorphous carbon depend on?
It’s method of manufacture and the conditions it is later subjected to
Where can amorphous carbon be found?
Naturally in coal and soot
Can be obtained by heating organic compounds to very high temperatures in the absence of their burning organic papers with insufficient oxygen