Green Chemistry Flashcards

1
Q

Is water vapour a greenhouse gas?

A

water is a greenhouse gas) because it absorbs infrared (IR) radiation (1)
The polarity of the water molecule changes when its bonds vibrate

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2
Q

Define greenhouse gas

A

(A greenhouse gas) traps/absorbs/ reflects IR (radiation) / heat (1)
(re-radiating) from the earth (1)

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3
Q

What does the relative greenhouse factor do?

A

​The relative greenhouse factor compares effect different greenhouse gases have at absorbing infrared radiation compared to CO2.

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4
Q

What is GWP?

A

​GWP (Global Warming Potential) is a measure of how much a given mass of greenhouse gas contributes to global warming. It’s determined by:
• ability to absorb infrared radiation (relative greenhouse factor)
• half-life in atmosphere - a measure of how long they last in the atmosphere before reacting & being broken down

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5
Q

What is IPCC?

A

​IPCC (Internal Panel on Climate Change) gives a possible error of +/- 35% in their figures. Shows how unreliable long-term predictions of climate change are.

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6
Q

What is anthropogenic climate change?

A

​Anthropogenic climate change is climate change caused by actions of human beings, e.g. burning fossil fuels, deforestation etc.

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7
Q

What is natural climate change?

A

​Natural climate change is climate change due to natural processes occurring on Earth, e.g. dissolving of CO2 in sea water & formation of carbonate rocks.

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8
Q

What are the most significant greenhouse gasses?

A

​The most significant greenhouse gases are CO2, CH4 & N2O.

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9
Q

How can a climate record be obtained?

A

​Ice cores removed by drilling deep samples from an ice sheet, e.g. polar icecaps of Antarctica/Greenland. Ice forms from a build-up of layers of snow every year, lower layers are older than upper layers, an ice core contains many years of layers. Properties of the ice/inclusions within the ice can be used to reconstruct a climactic record for the age range of the core.

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10
Q

How can ice cores be used to tell information?

A

​When the temperature falls, water molecules with heavier isotopes condense faster than normal water molecules. Relative concentrations of these in ice cores can be used to reconstruct local temperature changes.
​Air bubbles trapped in ice cores let scientists measure atmosphere concentrations of trace gases, such as CO2, CH4 & N2O.

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11
Q

Why does the amount of carbon dioxide is in the atmosphere fluctuate?

A

​About 45% of anthropogenic CO2 emissions remain in the atmosphere, 30% taken up by oceans & the rest taken up by trees & other plants. Of the CO2 that goes into the atmosphere, about 50% is removed over 30 years, 30% more in a few centuries & 20% will stay for many thousands of years.

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12
Q

What is a major cause of anthropogenic climate change?

A

air traffic. Jet aircraft produce frozen water vapour trails called contrails (water vapour is a greenhouse gas). They’re not officially classed as air pollution but can contribute to long-term changes in Earth’s climate. Jet engines also produce nitrogen oxides which are a greenhouse gas & destroy ozone.

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13
Q

What does carbon neutral mean?

A

​A fuel is carbon neutral if the amount of CO2 absorbed when the raw material was grown/
fuel was formed, is the same as produced when it’s manufactured & burned. E.g. trees are carbon neutral.

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14
Q

What are petroleum fuels? Are they is carbon neutral?

A

​Petroleum fuels were formed millions of years ago, by microorganisms that took CO2 from the atmosphere, and when burned produce CO2. They aren’t carbon neutral as the CO2 produced can’t be set against the CO2 absorbed in a reasonable time span (50 years).

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15
Q

What are biofuels?

A

​Biofuels, e.g. ethanol from maize, aren’t carbon neutral. The stages in production require energy generated by burning fossil fuels so gives out more CO2 than taken in.

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16
Q

Is burning hydrogen carbon neutral?

A

​Burning hydrogen isn’t carbon neutral. Despite H2O only being formed, hydrogen has to be manufactured; chemically from natural gas/electrolysis of H2O. CO2 is produced in manufacturing, construction & distribution.

17
Q

What is carbon footprint?

A

​A carbon footprint is a measure of the impact that human activities have on the environment in terms of greenhouse gas produced, measured in units of CO2. Can be seen as total CO2 & other greenhouse gases emitted over the life cycle of a product.

18
Q

How can carbon footprints be calculated?

A

They can be calculated using a LCA (Life Cycle Assessment) or can just include emissions resulting from energy use of fossil fuels.

19
Q

How does carbon footprint vary?

A

​Carbon footprint could be total amount of CO2 resulting from the actions of an individual in a year. This varies on different countries, e.g. India/China more CO2 is produced as industries develop yet the carbon footprint is low due to large population (counted per head).

20
Q

What is carbon offsetting?

A

​Companies & individuals can reduce the effect of their carbon footprint by carbon offsetting. E.g. paying for planting new trees/building a dam to produce hydroelectricity.

21
Q

What are the problems with ​CFCs & HCFCs?

A

​CFCs & HCFCs don’t occur naturally. CFCs in the upper atmosphere & destroy ozone, contributing to holes in the ozone layer. This increases harmful UV light reaching the Earth’s surface. The depletion of the ozone layer doesn’t make CFCs and HCFCs greenhouse gases, they also absorb infrared radiation.

22
Q

Why recycle?

A

This saves resources & reduces energy requirements. It’s cheaper to recycle glass than to create it. Recycling aluminium reduces the amount of electrolysis needed. This reduces electricity usage & less PFC (perfluorocarbon) gases are emitted, they’re 900 times more potent greenhouse gases than CO2.

23
Q

What happens to materials that can’t be recycled?

A

​Materials that aren’t recyclable need to be disposed of by incineration or in landfill sites. Incineration produces CO2 but gives out energy which can be used for heating. It can produce harmful chemicals, e.g. dioxins if it’s not carried out properly/the temperature is too low.

24
Q

What is the problem with landfill sites?

A

​Suitable landfill sites are less available so disposal of solid waste will become more problematic. Bacteria break down the waste, producing methane, so they’re monitored to prevent it escaping - it’s a greenhouse gas & can cause explosions. It can be used as a fuel but it’s difficult to get the steady amount required.

25
Q

Something

A

​Water with pollutants can’t be discharged into rivers/streams. Quality of water is monitored by Defra (Department for Environment, Food & Rural Affairs). Factories have to pay for every litre of water they use so reuse water whenever possible to save money & resources. Discharged water is usually stored & treated before being released. Harmful substances are precipitated & removed by settling/filtration.

26
Q

What are the problems with gases released from industries?

A

​Industrial waste gases include SO2, which can cause acid rain & is a greenhouse gas. It can be removed from gases using limestone.

27
Q

What is carbon capture?

A

​Carbon capture can reduce the amount of CO2 produced. We need to liquify the gas & pump it into old gas wells in the North Sea. It’s stored where natural gas used to be & could be stored under pressure on the sea bed.

28
Q

What have industries previously been using as fuel?

A

coal, oil & natural gas

29
Q

How can bio oil be produced from wheat?

A

​Wheat straw, which is renewable, can be converted into fuel by pyrolysis. This involves heating the straw in a limited O2 supply so it doesn’t burn; it can be heated by steam. In fast pyrolysis, it’s heated for a few seconds which breaks it down into a lot of relatively small molecules. It’s then cooled rapidly to prevent further reaction. Bio oil/pyrolysis oil is produced as well as char (carbon solids) & gases which can be used as fuels.

30
Q

How can ethanol be produced from organic waste?

A

​Ethanol can be produced by fermentation of plant material. Fermentation with yeast doesn’t fully convert all sugars so KO11, a genetically modified bacterium, is used instead. An advantage of using the bacteria rather than yeast is a wider range of sugars can be processed. This means bio waste that would usually be thrown away can be used.
​Farmers may grow crops specifically to make biofuels. This reduces the amount of food for the population.

31
Q

How can starch to be obtained?

A

​Starch is the main energy store for plants and is made up of glucose rings. It can be extracted as industrial starch. Increasing prices of crude oil means starch-based products are more popular, e.g. plastic bags are biodegradable.

32
Q

What can be made from starch?

A

adhesives, corrugated card, toothpaste and paints.

33
Q

Why is Lyocell/Tencel more advantageous than rayon?

A
  • Made using wood pulp from managed forests
  • Uses non-toxic, biodegradable solvent
  • It’s biodegradable & can be recycled
34
Q

What can woodpulp be used for?

A

​Wood pulp is a source of cellulose which be used to make polymers, e.g. cellulose ethanoate/acetate (fibres & photographic film) & rayon. It also makes 4-oxopentanoic acid which is used in pharmaceutical

35
Q

What is the disadvantage of catalysts?

A

they do often have to be replaced due to mechanical wear and tear.

36
Q

What is the best way to manufacture ethanoic acid?

A

​The best way to manufacture ethanoic acid is by reacting methanol with carbon monoxide:
CH3OH + CO —> CH3COOH