SHAPES OF MOLECULE Flashcards

1
Q

CH4 SHAPE AND BOND ANGLE

A

Tetrahedral

109.5

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2
Q

NH3 SHAPE AND BOND ANGLE

A

pyramidal

107

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3
Q

H20 SHAPE AND BOND ANGLE

A

Bent

104.5

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4
Q

BF3 SHAPE AND BOND ANGLE

A

trigonal planar

120

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5
Q

ELECTRONEGATIVITY DIFFERENCE OF A COVALENT BOND

A

0

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6
Q

ELECTRONEGATIVITY DIFFERENCE OF A POLAR COVALENT BOND

A

0 - 1.8

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7
Q

ELECTRONEGATIVITY DIFFERENCE OF AN IONIC BOND

A

more than 1.8

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8
Q

WHAT MAKES A BOND POLAR

A

when the bonded atoms have a different electronegativity value therefore the bonded electron pair is shared unequally

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9
Q

WHAT IS A DIPOLE

A

the separation of opposite charges

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10
Q

WHAT ARE INTERMOLECULAR FORCES and what is the order of strength

AND THE THREE CATEGORIES

A

weak interactions between dipoles of different molecules

London forces
Permanent dipole dipole interactions
Hydrogen bonding

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11
Q

What is electronegativity

A

the ability for an atom to attract electrons towards itself in a covalent bond

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12
Q

2 examples of polar covalent bonds

A

H-Cl H-O-H

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13
Q

Why is CO2 not polar

A

as it has 2 polar bonds that are arranged symmetrically so no overall polarity

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14
Q

What is an induced dipole-dipole

A

a temporary dipole created when atoms or molecules are near each other so electrons can move from one end to another

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15
Q

How are crystal structures held together

A

Induced dipole-dipole forces hold molecules together,(covalent bonds hold the atoms together)

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16
Q

What happens when you boil a liquid

A

You break the weak induced dipole-dipole forces, NOT THE COVALENT BONDS

17
Q

difference of boiling points of straight chain hydrocarbons and branched hydrocarbons

A

Straight chain hydrocarbons can pack together tighter, therefore there are more stronger induced dipole-dipole forces so the boiling point is high

Branched hydrocarbons cant pack together as close therefore the induced dipole-dipole forces are weaker and boiling point is therefore lower

18
Q

What is a dipole-dipole force

A

weak electrostatic force that exists between molecules with polarity

19
Q

What is a test for polar molecules

A

run a steady stream of the liquid near a charged rod, the liquid will bend towards the rod if polar as the molecules align to face the rod

20
Q

When does hydrogen bonding occur

A

when hydrogen on one molecule forms a bond with the lone pair on either nitrogen, oxygen or fluorine as they are very electronegative

21
Q

Trend in boiling points of hydrogen halides

A

HF, HI, HBr, HCl

HF has hydrogen bonding so will need the most energy to overcome the electrostatic forces, the other 3 do not, so as the mass of the molecule increases, so does the size of the electron cloud, and so more induced dipole-dipole forces