Section 5 - Pgs 66-69 Flashcards

1
Q

Why are most metals found in ores?

A

They are reactive so they easily form compounds - they are the ores.

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2
Q

What is a metal ore?

A

A compound found in the Earth’s crust from which a metal can be extracted.

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3
Q

What determines how easily a metal is extracted from its ore?

A

The more reactive the metal, the harder it is to extract from a compound.

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4
Q

What is a common compound type for metal ores?

A

Oxides

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5
Q

What is the extraction of a metal from its oxide ore called?

A

Reduction

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6
Q

What is the name for the chemical used to extract a metal from its oxide ore?

A

The reducing agent

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7
Q

What determines the way in which a metal is extracted from its ore?

A
  • If it is less reactive than carbon, it is heated with carbon to remove the oxygen
  • If it is more reactive than carbon, electrolysis is used
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8
Q

Why must aluminium be extracted using electrolysis?

A

It is more reactive than carbon, so the carbon will not ‘steal’ the oxygen from the aluminium.

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9
Q

What is the formula for aluminium ore?

A

Al2O3

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10
Q

What is aluminium ore called?

A

Bauxite (Aluminium oxide)

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11
Q

What is the melting point of aluminium oxide?

A

Over 2000*C

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12
Q

What is cryolite used for in aluminium extraction and why?

A

It is used to dissolve the aluminium oxide in. This is because it has a lower melting point (about 900*C) so it saves energy.

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13
Q

What is cryolite?

A

Another more rare aluminium ore, which has a lower melting point than aluminium oxide.

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14
Q

By what process is aluminium extracted?

A

Electrolysis

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15
Q

What are the electrodes in electrolysis made from?

A

Graphite

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16
Q

What happens at the anode during the extraction of aluminium from aluminium oxide by electrolysis?

A
  • O2- ions lose electrons to become O2 molecules

- These then react with the graphite anode to become CO2

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17
Q

What happens at the cathode during the extraction of aluminium from aluminium oxide by electrolysis?

A
  • Al3+ ions gain electrons to become Al atoms

- These then sink to the bottom

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18
Q

Why does the anode need to be replaced frequently during the electrolysis of aluiminium oxide?

A

The oxygen formed there reacts with the carbon to form CO2, which is wears down the anode.

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19
Q

What type of reaction is the electrolysis of aluminium oxide?

A

Redox

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20
Q

What is the half-equation for the anode during the electrolysis of aluminium oxide?

A

2O2- -> O2 + 4e-

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21
Q

What is the half-equation for the cathode during the electrolysis of aluminium oxide?

A

Al3+ + 3e- -> Al

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22
Q

At which electrodes do oxidation and reduction happen during the electrolysis of aluminium oxide?

A

Oxidation: Anode
Reduction: Cathode

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23
Q

Give the word eqauation for the decomposition of aluminium oxide by electrolysis.

A

Aluminium oxide -> Aluminium + Oxygen

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24
Q

Why is electrolysis so expensive?

A
  • It requires electricity
  • Lots of heat needed to melt cryolite (900*C)
  • Replacing anode
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25
What is the melting point of cryolite?
900*C
26
How is iron extracted?
Reduction using carbon in a blast furnace.
27
What is iron ore called?
Haematite (Iron oxide)
28
What is the formula for iron ore?
Fe2O3
29
What are the raw materials used in a blast furnace?
- Iron ore - Coke - Limestone (- Hot air)
30
What is coke?
Almost pure carbon
31
What is the chemical name for limestone?
Calcium carbonate
32
What is the forumla for limestone?
CaCO3
33
Remember to look at all the reactions in the blast furnace.
Pg 68 of revision guide
34
What are the products of the blast furnace?
- Molten iron - Slag - Waste gases
35
Give the reactions in the blast furnace.
``` Reducing the iron ore to iron: • C + O2 -> CO2 • CO2 + C -> 2CO • 3CO + Fe2O3 -> 3CO2 +2Fe Removing the impurities: • CaCO3 -> CaO + CO2 • CaO + SiO2 -> CaSiO3 ```
36
What is the temperature in the blast furnace?
About 1500*C
37
Give the reactions in the blast furnace used to reduce the iron ore.
* C + O2 -> CO2 * CO2 + C -> 2CO * 3CO + Fe2O3 -> 3CO2 +2Fe
38
Give the reactions in the blast furnace used to remove impurities.
* CaCO3 -> CaO + CO2 | * CaO + SiO2 -> CaSiO3
39
Where are slag and iron collected from the blast furnace?
At the bottom, because they are very dense and sink to the bottom.
40
What is the formula for slag?
CaSiO3
41
What does limestone decompose into in the blast furnace?
Calcium oxide and carbon dioxide
42
What is the main impurity which needs to be removed in the blast furnace?
Sand
43
What is the chemical name and formula for sand?
Silicon dioxide (SiO2)
44
What are some uses of slag?
* Road-building | * Fertiliser
45
What are some common properties of iron and aluminium?
* Dense * Lustrous * High melting points * Strong * Malleable * Good conductors of electricity and heat
46
What is the melting point of iron?
1538*C
47
What is the melting point of aluminium?
660*C
48
What are the different forms of iron?
* Wrought iron * Cast iron * Steel * Stainless steel
49
What is wrought iron and what are its properties and uses?
Almost pure iron -> Malleable | • Ornamental gates and railings
50
What is cast iron and what are its properties and uses?
Mixture of iron, carbon and silicon -> Hard but brittle • Manhole cover • Some cooking pans
51
What is steel and what are its properties and uses?
Mixture of iron, carbon and some other metals -> Hard but malleable • Car bodies • Girders
52
What is stainless steel and what are its properties and uses?
Mixture of iron and chromium -> Doesn't rust • Knives and forks • Cooking pans
53
What is the main problem with iron and how is this solved?
It rusts easily, which is solved by making stainless steel.
54
What is wrought iron made from and what are its properties?
Almost pure iron -> Malleable
55
What is cast iron made from and what are its properties?
Mixture of iron, carbon and silicon -> Hard but brittle
56
What is steel made from and what are its properties?
Mixture of iron, carbon and some other metals -> Hard but malleable
57
What is stainless steel made from and what are its properties?
Mixture of iron and chromium -> Doesn't rust
58
What are the main differences between the properties of iron and aluminium?
* Aluminium does not corrode as easily as iron. | * Aluminium is lighter than iron.
59
How do aluminium's properties determine its uses?
* Aluminium is light -> Bicycle frames + aeroplanes | * Aluminium doesn't corrode easily -> Drinks cans
60
Why doesn't aluminium corrode easily?
The aluminium reacts very quickly with the oxygen in the air to form a protective layer of aluminium oxide, which prevents any further corrosion.