Section 2 - Pgs 37-42 Flashcards
Why is all rain slightly acidic?
Carbon dioxide in the air reacts with water to produce a slightly acidic solution.
Carbon dioxide + Water ->
Carbon dioxide + Water -> Carbonic Acid
What percentages of what gases make up the atmosphere?
Nitrogen - 78%
Oxygen - 21%
Argon - Nearly 1%
Carbon Dioxide - 0.04%
What experiments can be used to investigate the proportions of oxygen in the atmosphere?
1) Heating copper in between syringes
2) Using iron to form rust (or phosphorus to form phosphorus oxide)
Describe how copper can be used to calculate the amount of oxygen in the air.
1) Set up an excess of copper oxide in the middle of two linked syringes.
2) Make sure the syringes contain 100cm3 of air.
3) Heat the copper until the reaction finishes.
4) The volume of air should reduce to about 80cm3, showing that there is approximately 20cm3 of oxygen in the air (which has reacted with the copper to form copper oxide).
Describe how iron (or phosphorus) can be used to calculate the amount of oxygen in the air.
1) Soak some iron wool in acetic acid (a catalyst) and push it into the bottom of a test tube.
2) Put your thumb over the end of the tube, invert it and put it upside down in a beaker of water.
3) Over time, the water level in the test tube will rise. This is because the oxygen in the air is used to make the iron rust and water rises to fill the gap.
4) Mark the start and end positions of the water.
5) Fill the tube up with water to each line and pour this into a measuring cylinder. The difference between the two volumes can be used to work out the percentage of oxygen in air. It should be about 20%.
A similar thing can be done with white phosphorus, which smoulders in air to produce phosphorus oxide.
What is the symbol equation for copper reacting with oxygen?
2Cu + O2 -> 2CuO
Describe how oxygen can be prepared in a lab.
1) Prepare some hydrogen peroxide (H2O2) and some manganese(IV) oxide catalyst in a conical flask.
2) The hydrogen peroxide decomposes into water and oxygen, which can be collected by:
a. Using a delivery tube to bubble the gas through a delivery tube and into a cylinder or gas jar filled with water.
b. Using a gas syringe.
(Diagram pg 38)
What does hydrogen peroxide decompose into?
Water and oxygen
What is the symbol equation for the decomposition of hydrogen peroxide?
2H2O2 (aq) -> 2H2O (l) + O2 (g)
What catalyst speeds up the decomposition of hydrogen peroxide?
Manganese(IV) oxide
What is formed when an element is burned?
An oxide
What does an element react with when it is burnt?
Oxygen
Do oxides have an acidic or basic character?
They can be either. It depends on the element reacting with oxygen.
Describe the reaction of magnesium burning in air and the products.
- Magnesium burns with a bright white flame
- Magnesium oxide formed, which is a white powder
What is the acidity of magnesium oxide when dissolved in water?
Slightly alkaline
What is the symbol equation for burning magnesium in air?
2Mg (s) + O2 (g) -> 2MgO (s)
Describe the reaction of carbon burning in air and the products.
- Carbon will burn if very strongly heated
- It has an orangey/yellowy flame
- Produces carbon dioxide gas
When will carbon dioxide react with oxygen?
When heated very strongly.
What is the acidity of carbon dioxide when dissolved in water?
Slightly acidic
What is the symbol equation for burning carbon in air?
C (s) + O2 (g) -> CO2 (g)
Describe the reaction of sulphur burning in air and the products.
- Sulphur burns with a pale blue flame
- Produces sulphur dioxide gas
What is the acidity of sulphur dioxide when dissolved in water?
Acidic
What is the symbol equation for sulphur burning in air?
S (s) + O2 (g) -> SO2 (g)
What are the two ways of producing CO2 in the lab?
1) Dilute acid reacts with calcium carbonate
2) Thermal decomposition of metal carbonates
In gas collection, when is an upwards and when is a downwards delivery used?
Depends on the density of the gas being collected.
1) Delivery tube is fed into a test tube either upwards or downwards.
2) Upwards delivery to collect ‘lighter than air’ gases (e.g. H2)
3) Downwards delivery to collect ‘heavier than air’ gases (e.g. CO2)
Describe how dilute acid reactions with calcium carbonate can be used to produce carbon dioxide in a lab.
1) Calcium carbonate (marble chips) is put in a flask and dilute hydrochloric acid is added.
2) Dilute HCl reacts with CaCO3 to produce calcium chloride, water and carbon dioxide gas.
3) Carbon dioxide gas is collect in a gas syringe or using downwards delivery.
(Diagram Pg 39)
What is the word equation for hydrochloric acid reacting with calcium carbonate?
Hydrochloric acid + Calcium carbonate -> Calcium chloride + Water + Carbon dioxide
What is the symbol equation for hydrochloric acid reacting with calcium carbonate?
2HCl (aq) + CaCO3 (s) -> CaCl2 (aq) + H2O (l) + CO2 (g)
Describe how the thermal decomposition of metal carbonates can be used to produce carbon dioxide in a lab.
1) Heat a metal carbonate (such as copper(II) carbonate) in a test tube.
2) Collect the gas using downward delivery through a delivery tube.
What is the word equation for the thermal decomposition of copper(II) carbonate?
Copper carbonate -> Copper oxide + Carbon dioxide