Section 4-Inorganic Chemistry P1 (pg35-40, pg51-53) Flashcards

1
Q

What is produced when group 1 elements react with oxygen?

What are some examples?

A
  • form metal oxides (this is why metals tarnish when left in the air- a dull metal oxide layer has formed)
  • Lithium->lithium oxide(Li₂O)
  • Sodium->sodium oxide(Na₂O) and sodium peroxide(Na₂O₂)
  • Potassium->potassium peroxide(K₂O₂) and potassium superoxide(KO₂)
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2
Q

What is produced in the reaction between group 1 elements and water?

A
  • they all react vigorously
  • the reaction produces a metal hydroxide and the solution is alkaline(hence they are called the alkali metals)
  • the reaction also produces hydrogen (hence the fizzing)
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3
Q

What happens to the reactivity of Group 1 as you move down the group?

A
  • Group 1 elements become more reactive as you go down the group
  • This is visible with their reactions with water: lithium takes the longest to react where as potassium takes the smallest amount of time, this trend is also visible with their reactions with oxygen
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4
Q

What is the general trend as you go down the halogens?

A
  • the elements have a darker colour
  • have a higher boiling point
  • reactivity decreases
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5
Q

What are the properties of Chlorine (Cl₂)?

A
  • green gas

- boiling point -34°C

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6
Q

What are the properties of Bromine (Br₂)?

A
  • red-brown liquid

- boiling point 59°C

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7
Q

What are the properties of Iodine (I₂)?

A
  • dark grey solid

- boiling point 185°C

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8
Q

What reactions go on with the halogens?

A

Displacement reactions- more reactive halogens will displace less reactive ones

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9
Q

What happens when Potassium chloride (colourless solution) is added to:

1) Chlorine water(colourless)
2) Bromine water(orange)
3) Iodine water(brown)

A

1) no reaction
2) no reaction
3) no reaction

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10
Q

What happens when Potassium bromide (colourless solution) is added to:

1) Chlorine water(colourless)
2) Bromine water(orange)
3) Iodine water(brown)

A

1) orange solution formed(because the bromine has been displaced by the chlorine)
2) no reaction
3) no reaction

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11
Q

What happens when Potassium iodide (colourless solution) is added to:

1) Chlorine water(colourless)
2) Bromine water(orange)
3) Iodine water(brown)

A

1) brown solution formed(because the iodine has been displaced by the chlorine)
2) brown solution formed(because the iodine has been displaced by the bromine)
3) no reaction

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12
Q

What do halogen displacement reactions involve?

A
Halogen displacement reactions involve the transfer of electrons. 
REDOX REACTIONS(oxidation and reduction happen simultaneously)
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13
Q

Define Oxidation:

A

Loss of electrons

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14
Q

Define Reduction:

A

Gain of electrons

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15
Q

What is OIL RIG?

A

O - oxidation
I - is
L - loss

R - reduction
I - is
G - gain

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16
Q

What main gases are in the atmosphere and what is the percentage composition?

A

Nitrogen - 78%
Oxygen - 21%
Argon - nearly 1%
Carbon Dioxide - 0.04%

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17
Q

What different ways can you test the amount of oxygen in the air?

A
  • IRON reacting with the air(will form rust)
  • PHOSPHORUS reacting with the air(phosphorus will react with oxygen in the air to make phosphorus oxide)
  • COPPER reacting with the air(will react to form copper oxide)
  • FLOATING CANDLE(the candle will burn and use the oxygen in the air)
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18
Q

Describe how iron wool (metal) can be used to work out how much oxygen there is in the air:

A
  • soak some iron wool in acetic acid(acid will catalyse the reaction), push the wool into a measuring cylinder, invert the measuring cylinder into a beaker of water
  • record the starting position of the beaker water level in the measuring cylinder
  • over time the water level in the measuring cylinder will rise(because the iron reacts with the oxygen and the water rises to fill the space the oxygen took up)
  • leave until the water level stops changing and then record the finishing position of the water in the measuring cylinder
  • then find the change in volume and divide it by the starting volume and times by 100
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19
Q

Describe how phosphorus can be used to determine the percentage of oxygen in the air:

A
  • place the phosphorus in a tube and attach a glass syringe at either end with 100cm³ air in one syringe and the other empty
  • heat the phosphorus and use the syringes to pass the air over the phosphorus(forming phosphorus oxide)
  • keep on sending air across it until the volume doesn’t change then do 100 - your starting volume to find out the percentage of oxygen in the air
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20
Q

When you burn something what does it react with?

A

When you burn something it reacts with OXYGEN in the air

-this forms an oxide (it can be acidic or basic)

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21
Q

What happens when you burn magnesium?

A
  • burns with a bright white flame
  • white power is formed(magnesium oxide)
  • magnesium oxide is slightly alkaline when dissolved in water
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22
Q

What happens when you burn hydrogen?

A
  • burns very easily with oxygen(can be explosive)
  • has an orangey/yellow
  • water is produced
  • often used as a test for hydrogen gas
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23
Q

What happens when you burn sulfur?

A
  • pale blue flame
  • produces sulphur dioxide
  • sulphur dioxide dissolved in water is acidic
24
Q

Describe the thermal decomposition of a carbonate to produce carbon dioxide and how you can collect the carbon dioxide:

A
  • heat metal carbonate -> carbon dioxide + metal oxide
  • thermal decomposition breaks down a substance into simpler substances
  • copper(II) carbonate(green solid) that will easily decompose to form carbon dioxide and copper(II) oxide(black solid)
  • collect the carbon dioxide using a bung delivery tube and a separate test tube
25
Q

What is the temperature of the earth determined by?

A

The balance between the heat the earth gets from the sun and the heat it radiates back out to space

26
Q

What are examples of greenhouse gases and what do they naturally do?

A

Carbon dioxide, methane, water vapour
-they act naturally as an insulating layer, they absorb most of the heat that would be normally be radiated back into space and re-radiate it towards the earth

27
Q

What are two examples of human activity which affects the amount of carbon dioxide in the atmosphere?

A
  • deforestation (so less carbon dioxide is removed from the atmosphere by photosynthesis)
  • burning fossil fuels (carbon that was trapped in these fuels are being released as carbon dioxide)
28
Q

How is increasing amounts of carbon dioxide in the air linked to climate change?

A

-there is a correlation between the increasing levels of carbon dioxide and global warming, although the earth’s temperature varies naturally the rate of increase in temperature is unnatural

29
Q

What are the effects of global warming?

A

Global warming is a type of climate change

  • it can cause:
  • > changing rainfall patterns
  • > severe flooding due to the polar ice caps melting and sea levels rising
30
Q

Describe how you carry out a flame test:

A
  • clean a platinum wire loop by dipping it in dilute HCl and then holding it in a flame
  • repeat until the wire burns without any colour, then dip the wire into your test sample and then put it into a non-luminous, non-roaring flame and look for the colour
31
Q

What charge have cations got?

A

positive

32
Q

What charge have anions got?

A

negative

33
Q

What test and result shows that lithium is present in a substance?

A

flame test

red flame

34
Q

What test and result shows that sodium is present in a substance?

A

flame test

yellow flame

35
Q

What test and result shows that potassium is present in a substance?

A

flame test

lilac flame

36
Q

What test and result shows that calcium is present in a substance?

A

flame test

orange-red flame

37
Q

What test and result shows that copper(II) is present in a substance?

A

flame test
blue-green flame
reacted with NaOH, coloured precipitate formed
blue precipitate

38
Q

Describe how you carry out a test to form a coloured precipitate with NaOH:

A
  • many hydroxides are insoluble so form precipitates when formed, some have characteristic colours
  • add a few drops of sodium hydroxide solution to your test solution
  • if you get a coloured precipitate formed then you can work out what cation is present
39
Q

What test and result shows that iron(II) is present in a substance?

A

reacted with NaOH, coloured precipitate formed

sludgy green precipitate

40
Q

What test and result shows that iron(III)is present in a substance?

A

reacted with NaOH, coloured precipitate formed

reddish brown precipitate

41
Q

Describe how you can carry out a test to see whether there is an ammonium compound present:

A
  • add your test substance to some sodium hydroxide
  • if ammonia gas has been produced you can find out buy placing a damp piece of red litmus paper and if ammonia is present then it will turn blue
42
Q

Describe how you can test for carbonates:

A
  • add HCl to your test sample
  • if carbonates are present then carbon dioxide will be released
  • test gas produced with lime water to see whether carbon dioxide has been produced
43
Q

Describe how you test for sulphates:

A
  • add HCl to your test substance and then barium chloride

- a white precipitate of barium sulphate means the original compound contain sulphate

44
Q

Why is hydrochloric acid added in the test for sulphates?

A
  • to get rid of any traces of carbonate or sulphite ions before you do the test
  • otherwise them two anions could compromise your test
45
Q

Describe how you test for the presence of the halide ions:

A

-add nitric acid to your test substance and then add silver nitrate solution

46
Q

What test and result shows that chloride ions are present in a substance?

A

add nitric acid and silver nitrate

white precipitate

47
Q

What test and result shows that bromine ions are present in a substance?

A

add nitric acid and silver nitrate

cream precipitate

48
Q

What test and result shows that iodide ions are present in a substance?

A

add nitric acid and silver nitrate

yellow precipitate

49
Q

Why is nitric acid added in the test for the halide ions?

A
  • to get rid of the carbonate or sulphate ions before the test
  • can’t use hydrochloric acid this time because chlorine is what you are testing for and it is already present in hydrochloric acid
50
Q

Describe the test for chlorine:

A

Damp blue litmus paper

if chlorine is present: litmus paper will turn red then will be bleached white

51
Q

Describe the test for Oxygen:

A

Glowing splint

if oxygen is present: the splint will relight

52
Q

Describe the test for Carbon Dioxide:

A

Bubble the gas through limewater

if carbon dioxide is present: limewater will go cloudy

53
Q

Describe the test for Hydrogen:

A

lit splint

if hydrogen is present: hear a squeaky pop

54
Q

Describe a test for Ammonia:

A

damp red litmus paper

if ammonia is present: litmus paper will turn blue

55
Q

What is a chemical test for the presence of water?

A

copper(II) sulphate crystals

  • wet it is blue, dry it is white
  • you can heat wet copper(II) sulphate to make it anhydrous
  • so you can use it to test for the presence of water
56
Q

What is a physical test for the purity of water?

A
  • test for either the boiling or freezing point

- only pure water will boil at 100°C and freeze at 0°C