scitf measuresments a calculations Flashcards

1
Q

Give a general description of measurement units

A
  • Units used in scientific measurements are the units of the «metric system»
  • First developed in France and accepted internationally in 1960.
  • Called SI units and composed of 7 base units.
  • Prefixes are used to indicate decimal fractions or multiples of various units
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2
Q

Name the SI base units (physical quantity, name of unit, and abbreviation)

A
  • Mass, kilogram, kg
  • length, meter, m
  • time, second, s^a
  • temperature, kelvin, K
  • amount of substances, mole, mol
  • electric current (elk. storm), ampere, A
  • luminous intensity (Lichtintensität), candela, cd
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3
Q

For what are prefixes used? Name them

A
  • to indicate decimal fractions or multiples of various units
  • Giga, G, 10^9
  • Mega, M, 10^6
  • kilo, k, 10^3
  • deci, d, 10^-1
  • centi, c, 10^-2
  • milli, m, 10^-3
  • micro,μ^a , 10^-6
  • nano, n, 10^-9
  • pico, p, 10^-12
  • femto, f, 10^-15
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4
Q

How does heat flow? How can you calculate Kelvin, C° , F by having C°, or Kelvin?

A
  • heat always flows spontaneously from a substance at higher temperature to one at lower temperature
  • Zero on the Kelvin scale is the lowest attainable temperature, -273.15°C, referred to as «absolute zero»
  • K = oC + 273.15
  • °C = 5/9 (F – 32)
  • T(°F) =T(°C) × 9/5 + 32
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5
Q

How is the volume of a cube given? Order graduated cylinder, syringe (Spritze), buret, pipet, flask depending on volume

A
  • The volume of a cube is given by its length cubed, (length)^3
  • 1 L = 1 dm3 = 1000 cm3 = 1000 mL
  • Syringe, buret, pipet > graduated cylinder > flask
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6
Q

How is the density defined?

A
  • It is the amount of mass in a unit volume of the substance:
  • > Density = mass / volume
  • The density of water is 1.00 g/cm3
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7
Q

What is stoichiometry?

A
  • Using a balanced chemical equation to calculate amounts of reactants and products is called stoichiometry
  • 1700s Lavoisier: law of conservation of mass
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8
Q

How is a chemical equations?

A
  • Determine the reactants and the products through experiments
  • Derive the chemical formulas
  • Write the unbalanced equation
  • Balance the equation by adding coefficients
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9
Q

What are the steps in stoichiometry?

A
  • first calculate n
  • > n= m/M
  • n (1.reactant) is equal to (2. Reactant) (amount has to be payed attention)
  • calculate m with formula -> m= M*n
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10
Q

How do alkali metals react?

A
  • Elements in the same group show similar reactivities

- All alkali metals, when reacting with water, form their hydroxides and hydrogen

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11
Q

What happens during combustion reactions?

A
  • Combustion (Verbrennung) reactions are fast reactions producing fire; most contain oxygen in the air as a reactant
  • During combustion, hydrocarbons (s.a. CH4) react with oxygen(2O2) to produce CO2 and H2O.
  • Compounds containing O in addition to C and H also produce CO2 and H2O during combustion (ex: glucose)
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12
Q

Give the reaction for potassium with water

A

-2K(s) + 2H2O(l) → 2KOH(aq) + H2(g)

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13
Q

How does an airbag work?

A
  • Decomposition of sodium azide (NaN3) inflates the car airbags
  • Due to collision, NaN3 decomposes very quickly and produces the nitrogen gas (N2) which inflates the airbag
  • 2NaN3 (s) -> 2Na (s) + 3N2 (g)
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14
Q

How is amu (atomic mass unit) defined? How is molecular weight defined?

A
  • 1 amu=1,66054x10^-24g and 1 g=6,02214x10^23 amu
  • Amu was defined by assigning 12 amu to carbon-12 isotope
  • Many elements are found in nature as a mixture of their isotopes
  • Molecular weight: total mass of atoms in the chemical formula
  • For ionic substances we use the term formula weight rather than molecular weight.
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15
Q

What is 1 mole?

A
  • amount of substance that contains as many objects (atom, molecule, etc.) as there are atoms in 12 g of carbon-12
  • 1 mole 12C atoms = 6.02 x 10^23 ^12C atoms
  • 1 mole H2O molecules = 6.02 x 10^23 H2O molecules
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16
Q

Molecular weight is equal to?

What is the molecular weight of 1 mole of glucose (C6H12O6) in grams?

A
  • Molecular weight in grams of any object is always numerically equal to its formula weight in amu
  • n=m/M
  • M= 6 (12) + 1 (12) +6 (16)= 180 g/mol
  • M= 180 ; n= 1M;
  • m= M* n = 180g
17
Q

Give the definition for theoretical yield and actual yield

A
  • Theoretical yield: amount of product obtained when all of limiting reactants react
  • Amount of product obtained in reality is called «actual yield»
  • Always: actual yield ≤ theoretical yield
18
Q

How is the theoretical yield calculated?

A

-Determine the number of moles of each reactant
-n= m/M (have to get moles)
(The reactant that has the smallest mole number is the limiting reagent)
-The multiply the ratio between the limiting reagent and the product by the number of moles of the limiting reagent used in the experiment
-n* M= m

19
Q

What is aqueous solution? What is water’s one of its most important properties?

A
  • Solutions where water is a solvent are called aqueous solutions
  • One of its most important properties is its ability to dissolve many other substances
  • Many important reactions around us involve molecules dissolved in water.
20
Q

Give the definition of solution, solvent, solute, concentration

A
  • Solution: homogenous mixture of 2 or more substances
  • Solvent: the substance in greater quantity in the mixture
  • Solute: Substance dissolved in the solvent
  • Concentration: amount of substance dissolved in a known amount of solution or solvent (c= n/V)
  • Molarity: there is 1.00 mole of solute in every one liter of a 1.00M solution
21
Q

How many grams of Na2SO4 are required to prepare 0.350 L of 0.500 M Na2SO4?

A
  • c= n/V; C= 0.500M , V=0.350L

- n=m/M

22
Q

What is important to know about dilution?

A
  • Solutions used in the lab.s are mostly prepared or bought as concentrated solutions (stock solutions)
  • Less concentrated solutions can be obtained by the addition of water: dilution.
  • When diluting concentrated acids and bases, always acid and base should be added to water, not the other way around!
23
Q

Give the formula for dilution

A
  • Number of moles before dilution = number of moles after dilution
  • > M(before) V(before) = M(after) V(after)
24
Q

We would like to prepare 250 mL of 0.10M CuSO4 by diluting 1.0M of CuSO4. How can we achieve this?

A

V=250*0.1/1

25
Q

Compare salt and sugar in water (their properties)

A

-Substances whose aqueous solution contains ions and conducts electricity are called electrolytes
Those which do not ionize are called nonelectrolytes
-Ionic compounds ionize when dissolved in water
-When molecules are dissolved in water, they do not ionize, molecules only get dispersed (verteilt) in water

26
Q

What are strong/weak electrolytes?

A
  • Strong electrolytes: all ionic compounds and a few molecular compounds which exist in ionized form in solution.
  • Weak electrolytes: some molecular compounds which barely ionize when dissolved
  • Do not confound (verwechseln) solubility (Löslichkeit) and weak/strong electrolytes!
27
Q

Name some examples for weak and strong electrolytes

A

-weak=HF, AgCl, PbCl2, HC2H3O2, NH3
-strong=HCl, H2SO4, NaCl, NH4Cl, KOH, Ba(OH)2, KNO3
(-non-electrolytes= C12H22O11 (Table sugar), CH3OH, C2H5OH, CH3CH2OH, C6H12O6 (Glucose))