Reversible Reactions and Industrial Processes Flashcards
What is an example of a reversible reaction
Unhydrated copper sulphate + water = hydrated copper sulphate
What is the equation for the reversible copper sulfate reaction
CuSO(4) + H(2)O = CuSO(4) H(2)O
How do we test for water in a copper sulfate and water reaction
Using anhydrous copper sulfate
What is a closed system
Where reactants and products can’t escape
What happens eventually with reversible reactions
They reach an equilibrium
Name the process used to make ammonia
The haber process
What chemicals are combined in the haber process to make ammonia
Hydrogen and nitrogen
What conditions are used in the haber process to stop reactions from reversing
- Temperatures of about 450 degreees
- High pressure (200 atmospheres)
- An iron catalyst speeds up reactions
What is the effect of a higher temperature with reversible reactions
To push the reaction in the direction of the smallest total number of molecules - this benefits producing ammonia, as it is a single product that has two reactants
Why do high temperatures favour the backward reactions
Because the forward reaction is exothermic, and the backward reaction endothermic. High temperatures favour endothermic reactions.
Why isn’t the haber process run at a very low temperature
Because below 400 degrees the reaction rate is too slow for profit
What yield does a moderately high temperature give in a reasonable amount of time
15%
How is ammonia removed from the cycle
It is liquified, while hydrogen and nitrogen just pass through the system repeatedly
What makes ammonia identifiable
It is the only common gas which is an alkine
What are distinctive qualities of ammonia
It has a sharp choking smell
What is the formula for an ammonium ion
NH(4)(+)
What happens when ammonium sulfate is mixed with sodium hydroxide and the mixture is heated
Ammonia is given off
Give the equation for when ammonium sulfate and sodium hydroxide are mixed and heated
NH(4) + OH = NH(3) + H(2)O
What is the last way to identify ammonia
Using hydrogen chloride gas - white smoke is made
What do most fertilisers contain
Ammonia compounds, phosphorous and potassium
What are the environmental problems with fertilisers
- The fertiliser stimulates plant growth in water
- The fastest growing plants are single celled organisms
- An algal bloom is created
- Everything in the water eventually dies
What is the most commonly used fertiliser compound
Ammonium nitrate
How is ammonium nitrate produced (equation por favor)
By neutralising ammonia solution with nitric acid
NH(3) + HNO(3) = NH(4)NO(3)
Ammonia + nitric acid = ammonium nitrate
What is the reaction to mate ammonium nitrate known as
Neutralisation reaction