Reversible Reactions and Industrial Processes Flashcards

1
Q

What is an example of a reversible reaction

A

Unhydrated copper sulphate + water = hydrated copper sulphate

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2
Q

What is the equation for the reversible copper sulfate reaction

A

CuSO(4) + H(2)O = CuSO(4) H(2)O

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3
Q

How do we test for water in a copper sulfate and water reaction

A

Using anhydrous copper sulfate

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4
Q

What is a closed system

A

Where reactants and products can’t escape

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5
Q

What happens eventually with reversible reactions

A

They reach an equilibrium

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6
Q

Name the process used to make ammonia

A

The haber process

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7
Q

What chemicals are combined in the haber process to make ammonia

A

Hydrogen and nitrogen

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8
Q

What conditions are used in the haber process to stop reactions from reversing

A
  • Temperatures of about 450 degreees
  • High pressure (200 atmospheres)
  • An iron catalyst speeds up reactions
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9
Q

What is the effect of a higher temperature with reversible reactions

A

To push the reaction in the direction of the smallest total number of molecules - this benefits producing ammonia, as it is a single product that has two reactants

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10
Q

Why do high temperatures favour the backward reactions

A

Because the forward reaction is exothermic, and the backward reaction endothermic. High temperatures favour endothermic reactions.

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11
Q

Why isn’t the haber process run at a very low temperature

A

Because below 400 degrees the reaction rate is too slow for profit

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12
Q

What yield does a moderately high temperature give in a reasonable amount of time

A

15%

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13
Q

How is ammonia removed from the cycle

A

It is liquified, while hydrogen and nitrogen just pass through the system repeatedly

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14
Q

What makes ammonia identifiable

A

It is the only common gas which is an alkine

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15
Q

What are distinctive qualities of ammonia

A

It has a sharp choking smell

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16
Q

What is the formula for an ammonium ion

17
Q

What happens when ammonium sulfate is mixed with sodium hydroxide and the mixture is heated

A

Ammonia is given off

18
Q

Give the equation for when ammonium sulfate and sodium hydroxide are mixed and heated

A

NH(4) + OH = NH(3) + H(2)O

19
Q

What is the last way to identify ammonia

A

Using hydrogen chloride gas - white smoke is made

20
Q

What do most fertilisers contain

A

Ammonia compounds, phosphorous and potassium

21
Q

What are the environmental problems with fertilisers

A
  • The fertiliser stimulates plant growth in water
  • The fastest growing plants are single celled organisms
  • An algal bloom is created
  • Everything in the water eventually dies
22
Q

What is the most commonly used fertiliser compound

A

Ammonium nitrate

23
Q

How is ammonium nitrate produced (equation por favor)

A

By neutralising ammonia solution with nitric acid
NH(3) + HNO(3) = NH(4)NO(3)
Ammonia + nitric acid = ammonium nitrate

24
Q

What is the reaction to mate ammonium nitrate known as

A

Neutralisation reaction

25
What is another compound used for fertilisers
Ammonium sulfate (another neutralisation reaction)
26
Give the equation to make ammonium sulfate
2NH(3) + H(2)SO(4) = (NH(4))(2)SO(4)
27
What is sulfuric acid used for
- Making ammonium sulfate feriliser - It's the acid in vehicle batteries - Making fibres, paints and dyes - Dehydrating agent
28
What does the reaction of sulfuric acid with sugar demonstrate
Its power as a dehydrating agent
29
What is the formula for sucrose (sugar)
C(12)H(22)O(11) - The same proportions of hydrogen and oxygen as in water
30
What happens when sucrose reacts with concentrated sulfuric acid
The hydrogen and oxygen are removed leaving only carbon
31
What kind of reaction happens between sucrose and sulfuric acid
An exothermic one - the sugar basically caremalises and then turns black, and some of the water is evaporated, but gets stuck in the hardening carbon, causing the whole thing basically to grow
32
What is sulfuric acid made by
The contact process
33
What are the stages of the contact process
1. The manufacture of sulfur dioxide 2. The conversion of sulfur dioxide into sulfur trioxide 3. The conversion of sulfur trioxide into sulfuric acid
34
How is sulfur dioxide made and what's the equation
By burning sulfur in excess oxygen (irreversible) S + O(2) = SO(2) Excess oxygen is used because the next stage needs the rest of it
35
What does stage 2 of the contact process involve (equations)
Sulfur dioxide reacts with oxygen to make sulfur trioxide (reversible) 2SO(2) + O = 2SO(3)
36
What conditions is stage two of the contact process done under
- 450 degrees (same reasons as haber) - Normal pressure - Vanadium oxide as a catalyst
37
What does stage 3 of the contact process involve
Sulfur trioxide reacts with water to make sulfuric acid, but the reaction is uncontrollable, so the sulfur trioxide has to be dissolved first for safety reasons
38
What's the equation for making oleum
H(2)SO(4) + SO(3) = 2H(2)S(2)O(7)
39
What's the equation for making sulfuric acid
H(2S(2)O(7) + H(2)O = 2H(2)SO(4)