Resin Composites Flashcards

1
Q

What are the four components of composites?

A
  1. Matrix made of ORGANIC polymers
  2. Fillers made of inorganic particles such as glass or cermaics
  3. Coupling agents: Inorganic compound that bonds matrix and filler
  4. Initiator-Accelerator Systems
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2
Q

Ceramic have very ______ while polymers have very ______.

This makes resin composites fall ________ in terms of mechanical strength.

A

very high mechanical properties

Very low mechanical properties

Resin composites fall right between ceramic and polymers

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3
Q

What are the two most common resins?

Both of these are ________ and _________liquids.

A

Dimethacrylate (Bis-GMA)

Urethane dimethacrylate (UDMA)

Oligomers and viscous liquids

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4
Q

How do we reduce viscosity of __________ and ____________ ?

A

Bis-GMA ,UDMA

Add low molecular weight dimethacrylates such as TEGDMA and Bis-EMA6

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5
Q

Why is it important to reduce viscosity of resin composites?

A

To facilitate manipulation

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6
Q

What is the advantage of acrylic resins?

A

Lower polymerization shrinkage

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7
Q

Fillers can make up _________ to _____ in weight of the composite.

They control the ________ such as _______ and are usually particles of _______.

A

30-70% in weight of the composite

properties of the composite such as mechanical, water sorption, shrinkage

Particles of Glass

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8
Q

What glass is used in fillers?

A

Ceramics such as quartz, lithium aluminum silicate

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9
Q

What controls the properties of the composite?

A

Fillers

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10
Q

Radiopaque fillers include

A

barium
strontium
zinc
borosilicates
aluminosilicates

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11
Q

Fillers can reduce _________.

A

Shrinkage

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12
Q

What are the three categories of filler size?

A

Fine : 0.2 ro 3 micrometers/microns

Microfine : 0.04 microns

Nanofine: 1-100 NANOmeters

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13
Q

________ which are about _________ in size can agglomerate and form a ________

A

Nanofine, 1-100 NANOmeters, nanocluster

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13
Q

______ nanometers = _______ micrometer/micron

A

1000 = 1

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14
Q

The size-distribution of fillers can be split into _______ and _______.

A

Hybrids: Different Sizes

Filled: Similar sizes

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15
Q

What are two other options of fillers?

A
  1. Fiber-reinforced

Glass Fibers or Polyethylene or Aramid

  1. Nano-tubes

Carbon
Halloysite
Ceramics, Carbides, Zinc Oxide ..

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16
Q

Fiber-reinforced fillers include ______, ______ and ________.

_________ are ______ cost and have good adhesion

______ have __________ and poor adhesion

A

glass fibers, polyethylene fibers and aramid fibers

Glass , low cost, good adhesion

Polyethylene Fibers , enhanced mechanical properties, poor adhesion

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17
Q

Macrofill

A

10-50 micrometer sized particles

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18
Q

Microfill

A

40-50 NANOmeter sized particles that agglomerate

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19
Q

Hybrid

A

Some Macrofill (10-50 microns)
Some Microfill (40-50 nm)

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20
Q

Midifill

A

1-10 microns

40 nanometer

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21
Q

Minifill

A

0.6-1 microns

40 nanometer

22
Q

Nanofill

A

5-100 NANOmeters

23
Q

We can classify composites by consistency

________ composites have better ________/______. It reduces _________ but also reduces __________.

_________ allows formation of ____________ and has modified ___________ or other types of ________.

A

Flowable, adaptation/dispensing

Filler content but also reduces mechanical properties

Packable , tight interproximal contacts

filler size distribution or other types of fillers

24
What are bioactive fillers/monomers?
They prevent secondary caries and regenerate tissue?
25
What are the 3 types of bioactive monomers?
Antibiofilm/bacterial/fungal Remineralizing/Regeneration Acid Neutralizing
26
___________(4) are all bioactive fillers that are have _________ properties
Silver QA ZINC Antibiofilm/bacterial/fungal
27
___________is a bioactive filler that are have _________ properties
Calcium Phosphate (CaP) Remineralizing/Regeneration
28
___________is a bioactive filler that are have _________ properties
CaP fillers Acid neutralizing
29
Calcium phosphate is a ________ that has both ________ and _______ properties.
Bioactive filler Acid Neutralizing, Regenerative/Remineralizing
30
Coupling agents are responsible for ___________. They enhance _______ and minimize _______.
being the glue that bonds INORGANIC fillers with organic resin matrix. Enhances mechanical properties of composite Minimizes water absorption (hydrophobic environment)
31
What is the most common agent in coupling gents?
Silane
32
________ are often added to coupling agents.
INORGANIC pigments/oxides ( of iron) Flourescent Agents for whitening effect
33
There are three ways to cure composite. What are they?
1. Light 2. Chemical Reaction 3. Dual Initiated
34
Light curing is done with ___ light at wavelength _________ in the _____ spectra. Initiator: Accelerator:
blue , 465 NANOmeters, visible light Initiator: Camphorquinone added in 0.1-1% OR Diketone-amine Accelerator: Organic amines such as DAEMA
35
What are the two initiators of light curing?
Camphorquinone added in 0.1-1% OR Diketone-amine
36
__________ is a type of curing light made of _____________. It has _______ at ______ wavelengths and has an __________ operating temperature. It has a life of ________.
Quart Tungsten Halogen Quartz Bulb Filtered Light - 400-500 nm Elevated operating temperature 100 hrs
37
_______is a type of curing light made of __________. It has a ____________ light spectrum and __________ generation. Its life is __________.
LED Semiconductors narrow light spectrum and low heat 1000 hrs
38
How can we calculate the power intensity for different curing lights ?
Total Energy = Light Irradiance x Duration
38
What is light irradiance? What is the formula?
How powerful the curing light is
39
What is the unit for light irradiance?
mW/cm^2
40
Light is ________ inside the composite due to _______. The tip of the curing lamp should be within ________ of the surface.
Scattered 1mm
41
What can measure light irradiance?
Radiometer
42
Chemical Activation Initiator Accelerator How fast does it set?
Organic peroxides like benzoyl peroxide that produces free radicals 3-5 minutes
43
What is the result of inadequate polymerization?
Poor resistance to wear Poor color stability Secondary Caries Adverse soft tissue/pulp reactions Cytotoxicity
44
Volumetric shrinkage during polymerization can cause ________.
Contraction stress
45
The _______ of the composite _______ linearly with the volume fraction of ________. The _______ is dominated by the amount of ________.
strength / increases linearly with volume fraction of filler elastic modulus/stiffness is dominated by the amount of filler
46
Opalescence varies by ______ and ________ of filler. As the amount of same filler increases, translucency _________.
size and amount decreases
47
Water sorption causes the ________ of composite due to ___________. This can relieve __________ and is a much ________ process than polymerization shrinkage. After ______ , majority expansion is reached and it takes _______ to equilibrium
expansion, uptake of water polymerization stress and is a much slower process 4 days, 7 days
48
Water sorption is greater for _________ and evidenced as _______. It is also higher in _________ compared to ________ filler.
uncured composites, color instability microfilled than microhybrid.
49
Hardness is related ___________ to the volume fraction of filler. Strength increases _________ to the volume fraction of filler.
exponentially linearly
50
Higher hardness materials are more _______ to polish.
More difficult
51
Radiopacity is proportional to the amount of __________.
FILLER