Refinery processes Flashcards

0
Q

what is separation process ?

A

atmospheric distillation
vacuum distillation
light ends recovery (gas processing)

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1
Q

name the 3 refinery processes

A

separation
conversion
treatment

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2
Q

what does the separation process involve?

A

crude oil gets separated into its major components by distillation and desalting

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3
Q

atmospheric distillation

A

distillation at atmospheric pressure. liquids w lowest boiling pts evaporate first

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4
Q

vacuum distillation?

A

distillation at a reduced pressure to separate higher boiling point fractions from crude

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5
Q

light ends recovery

A

non condensable gases get separated from condensable gases

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6
Q

fractionation?

A

separation of crude oil into its more vs

uable/ usable components via distillation

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7
Q

distillation?

A

process of heating, vaporizing, fractionation and condensation of different boiling pt fractions of crude oil

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8
Q

petroleum conversion process

A
cracking
reforming
alkylation
polimerization
isomerization
coking
visbreaking
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9
Q

petrol conv

cracking?

A

high mol wt molecules broken down into smaller mol wt molecules in presence of a catalyst or high temp

a) thermal cracking ( heat lg hydrocarbons to high Temp)
b) catalytic cracking (catalyst speeds up rxn eg zeolite) 2 kinds

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10
Q

types of catalytic cracking?

A

fluid catalytic cracking - hotfluid catalyst cracks heavy gas oil into diesel and gas
hydrocracking- reduce sulfur by catalyst, lower temp and high pressure

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11
Q

catalyst?

A

chemical that can stimulat a chemical rxn without being consumed in that rxn

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12
Q

petrol conv

reforming?

A

rearranges naphtha to get higher octane

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13
Q

octane number

A

measure of resistamce to knock
compare the gas to isooctane and n heptane

pure iso octane 100% octane
pure n heptane 0% octane

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14
Q

petr conv

alkylation

A

conversion of light unsaturated open chain HC to high octane gas components

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15
Q

petr conv

polymerization

A

smaller molecules get combined to form larger ones

16
Q

petr conv

isomerization

A

straight chain HC converted to branched

17
Q

petr conv

coking?

A

residual from distillation tower is heated to above 900C and it cracks to oil, gas and naphtha. the heavy, pure carbon residue is coke

18
Q

petr conv

visbreaking?

A

reduction of viscosity of heavy wt oil producing tar

19
Q

petrl treating- steps

A
hydrodesulfurization
hydrotreating
chemical sweetening
acid gas removal
deasphalting
dewaxing
20
Q

petr treat

hydrodesulfurization?

A

remove sulfur in the presence of hydrogen from naphtha, gas, kerosene, jet fuel, diesel fuel and lube oil

21
Q

petr treat

hydrotreating

A

remove nitrogen and aromatic saturation of Hc stream

22
Q

petr treat

sweetening?

A

remove co2, hs, mercaptans ( cmpds w H S and C found in sour crude oil

23
Q

petr treat

acid gas removal?

A

remove co2 and h2s

24
Q

petr treat

deasphalting?

A

removal of asphaltenes ( soluble in benzene amd toluene and insoluable in heptane)
remove metals and sulfurs

25
Q

petr treat

dewaxing?

A

remove waxy molecules from heavy distillate fuel cuts or lube distillates