Redox Flashcards
oxidation
increase in oxidation number gain of oxygen loss of hydrogren loss of electrons
reduction
decrease in oxidation number loss of oxygen gain of hydrogen gain of electrons
redox reaction
one in which there are changes in oxidation number
oxidising agent
oxidises another species reduced itself takes electrons
reducing agent
reduces another species oxidised itself forces its electrons onto other species
oxidation state/number
made up construct treats every element as if it was ion
elements always
0
compounds add up to
0
polyatomic ions add up to
charge
simple ions
oxidation number = charge
group 1, 2, 13
always +1, +2, +3
fluorine always
-1
hydrogen almost always
+1
oxygen almost always
-2
chlorine usually
-1
oxidation number of F in F2
0
reactivity
how easily something reacts
best metallic oxidising agent
less reactive bc easier to gain electrons
best metallic reducing agent
more reactive bc easier to lose electrons
how does a voltaic cell work?
chemical reaction generates electricity
electrolysis
electric current drives reactions of oxidation and reduction - stalbe compounds are broken down into their elements
reactivity series
list of relative strengths of metals as reducing agents
what will more reactive metals do in redox reaction equations?
go from atoms to ions
disproportionation
reactions in which the same element is simultaneously oxidised and reduced
why is the dissolved oxygen content of water the most important indicators of water quality?
as the level of pollution in water increases, the dissolved oxygen content generally decreases
biological oxygen demand (BOD)
amount of oxygen used to decompose the organic matter in a sample of water over a specified time period
high BOD
indicates greater quantity of degradable organic waste in the water
voltaic cell diagram and explanation

cell diagram convention

saltbridge
- strip or glass tube containing aqueous solution of ions
- movement of ions neutralizes any build up of charge and maintains potential difference
- anions in salt bridge from from cathode to anode (opposes flow of electrons in exernal circuit)
- KNO3
- ions do not interfere with reactions at electrodes
- without saltbridge, no voltage is generated
electrolyic cell
uses an external source of electrical energy to bring about a reox reaction that would otherwise be non-spontaneous
electrolyte
molten ionic compound
electrodes
- redox reactions occur here
- electrodes remove charge on ions leaving electrically neutral products
electrolyic cell diagram and explanation
- electrodes made from conducting substance and connected to power supply
- inert because do not take part in redox reaction
- electrodes cannot touch
