Acid Deposition Flashcards
Is rain naturally alkali or acid?
acid because of presence of dissolved carbon dioxide - forms weak acid carbonic acid
What are the equations of rain water?

acid rain
- solutions with a pH below 5.6
- contain additional acids
what are the main contributors to acid rain?
- oxides of sulfur and nitrogen
- primary pollutants
is acid rain a primary or secondary pollutant?
secondary pollutant
acid deposition
all processes by which acidic components as precipitates or gases leave the atmosphere
what are the two types of acid deposition?
- wet acid deposition
- dry acid deposition
wet acid deposition
rain, snow, fog fall to ground as aqueous precipitates
dry acid deposition
gases fall to ground as dust and smoke and dissolve in water to form acids
sulfur oxide equations
either 1,2 or 1,2,3,4

nitrogen oxide equations
- either 1,3 or 2
- THEN
- either 4 or 5

impact on limestone for sulfur dioxide, sulfuric acid and nitric acid equations
erodes buildings and statues

impact on metals for sulfur dioxide, sulfuric acid and nitric acid
- increases rate of rusting
- removes oxide layer on metal surfaces like Al

impact of acid rain on plant life
- slows growth and injures plants through leaching
- dry deposition blocks pores for gas exchange
leaching
acid rain causes important minerals (Mg2+, Ca2+, K+) held in soil to become soluble and wash away before they can be absorbed by plants
acid deposition impact on water
- lakes become too acid to support life
- eutrophication occurs

eutrophication
- over-fertilization of bodies of water caused by nitrates in acid rain
- results in algal blooms leading to oxygen depletion
acid deposition impact on health
- sulfate and nitrate particles irritate respiratory tract
- increase risk of asthma, bronchitis and emphysema
- irritate eyes
pre-combustion methods of reducing SO2 emissions
- processes that reduce or remove sulfur present in coal or oil before combustion
- crush coal and wash with water: high density sulfide sinks to bottom and separates from clean coal
- hydrodesulfurisation: catalytic process that removes sulfur from refined petroleum products by reacting it with hydrogen to form hydrogen sulfide, used to manufacture sulfuric acid
post-combustion methods of reducing SO2 emissions
flue-gas desulfurization: wet slurry reacts with SO2 to form neutral calcium sulfate - used to make plasterboard

reduction of NOx emissions
- catalytic converters in vehicles: hot gases mixed with air pass over a platinum catalyst which converts toxic emissions into harmless products (picture = equation)
- lower temperature combustion: recirculating exhaust gases back into engine lowers temperature to reduce emissions
- lower demand for fossil fuels

method to restore acid rain damaged ecosystems
lime neutralises acid
