Acid Deposition Flashcards

1
Q

Is rain naturally alkali or acid?

A

acid because of presence of dissolved carbon dioxide - forms weak acid carbonic acid

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2
Q

What are the equations of rain water?

A
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3
Q

acid rain

A
  • solutions with a pH below 5.6
  • contain additional acids
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4
Q

what are the main contributors to acid rain?

A
  • oxides of sulfur and nitrogen
  • primary pollutants
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5
Q

is acid rain a primary or secondary pollutant?

A

secondary pollutant

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6
Q

acid deposition

A

all processes by which acidic components as precipitates or gases leave the atmosphere

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7
Q

what are the two types of acid deposition?

A
  • wet acid deposition
  • dry acid deposition
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8
Q

wet acid deposition

A

rain, snow, fog fall to ground as aqueous precipitates

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9
Q

dry acid deposition

A

gases fall to ground as dust and smoke and dissolve in water to form acids

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10
Q

sulfur oxide equations

A

either 1,2 or 1,2,3,4

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11
Q

nitrogen oxide equations

A
  • either 1,3 or 2
  • THEN
  • either 4 or 5
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12
Q

impact on limestone for sulfur dioxide, sulfuric acid and nitric acid equations

A

erodes buildings and statues

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13
Q

impact on metals for sulfur dioxide, sulfuric acid and nitric acid

A
  • increases rate of rusting
  • removes oxide layer on metal surfaces like Al
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14
Q

impact of acid rain on plant life

A
  • slows growth and injures plants through leaching
  • dry deposition blocks pores for gas exchange
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15
Q

leaching

A

acid rain causes important minerals (Mg2+, Ca2+, K+) held in soil to become soluble and wash away before they can be absorbed by plants

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16
Q

acid deposition impact on water

A
  • lakes become too acid to support life
  • eutrophication occurs
17
Q

eutrophication

A
  • over-fertilization of bodies of water caused by nitrates in acid rain
  • results in algal blooms leading to oxygen depletion
18
Q

acid deposition impact on health

A
  • sulfate and nitrate particles irritate respiratory tract
  • increase risk of asthma, bronchitis and emphysema
  • irritate eyes
19
Q

pre-combustion methods of reducing SO2​ emissions

A
  • processes that reduce or remove sulfur present in coal or oil before combustion
  • crush coal and wash with water: high density sulfide sinks to bottom and separates from clean coal
  • hydrodesulfurisation: catalytic process that removes sulfur from refined petroleum products by reacting it with hydrogen to form hydrogen sulfide, used to manufacture sulfuric acid
20
Q

post-combustion methods of reducing SO2 emissions

A

flue-gas desulfurization: wet slurry reacts with SO2 to form neutral calcium sulfate - used to make plasterboard

21
Q

reduction of NOx​ emissions

A
  • catalytic converters in vehicles: hot gases mixed with air pass over a platinum catalyst which converts toxic emissions into harmless products (picture = equation)
  • lower temperature combustion: recirculating exhaust gases back into engine lowers temperature to reduce emissions
  • lower demand for fossil fuels
22
Q

method to restore acid rain damaged ecosystems

A

lime neutralises acid