Reactivity trends Flashcards
metal + acid
metal + acid –> salt + hydrogen
Group 2 metal oxide + water
metal oxide + water –> OH- ions (alkaline solution)
Solubility of hydroxides in water
Increases down the group
States of halogens
Fluorine: gas
Chlorine: gas
Bromine: liquid
Iodine: solid
Why do halogens increase in melting point down the group?
- More electrons
- Greater London forces
- Stronger bonds
What happens to halogens in redox?
Reduced (they’re oxidising agents)
Reactivity in halogens and why
Decreases down the group
- Needs to gain electrons
- Greater distance
- Less nuclear attraction + more shielding
- Lower reactivity
What’s chlorine used for?
- Making bleach
- Water treatment (disinfectant)
Carbonate test
- Add dilute nitric acid
- Bubble gas through limewaater
Silver nitrate halide test
- Add AgNO3 to halide solution
- Colored precipitates are formed
- Add aq ammonia to test solubility
Silver halide precipitate colours
Silver chloride: white (soluble)
Silver bromide: cream (soluble)
Silver iodide: yellow (insoluble)
Sequence of test for anions
1) carbonates
2) sulfates
3) halides
Cation test for ammonium
- Add aq NaOH
- Ammonia gas is produced
Group 2 metal + water
metal + water –> metal hydroxide + hydrogen
Chlorine + water
chlorine + water –> chloric acid + hydrochloric acid